(E)-ethyl-3-((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl)oxiran-2-yl)acrylates

Base Information

Chemical Name:(E)-ethyl-3-((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl)oxiran-2-yl)acrylates
CAS No.:1005776-31-7
Molecular Formula:C₁₇H₂₂O₅
Molecular Weight:306.359
Hs Code.:

Synonyms:(E)-ethyl-3-((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl)oxiran-2-yl)acrylates

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-ethyl-3-((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl)oxiran-2-yl)acrylates

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Technology Process of (E)-ethyl-3-((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl)oxiran-2-yl)acrylates

There total 10 articles about (E)-ethyl-3-((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl)oxiran-2-yl)acrylates which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1099-45-2
ethyl (triphenylphosphoranylidene)acetate

: 794527-59-6
(2R,3S)-3-[2-(4-Methoxy-benzyloxy)-ethyl]-oxirane-2-carbaldehyde

: 1005776-31-7
(E)-ethyl-3-((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl)oxiran-2-yl)acrylates

Guidance literature:: In benzene; at 20 ℃; for 12h;
DOI:10.1016/j.tetlet.2007.11.107

Reference yield:

: 867-13-0
diethoxyphosphoryl-acetic acid ethyl ester

: 794527-59-6
(2R,3S)-3-[2-(4-Methoxy-benzyloxy)-ethyl]-oxirane-2-carbaldehyde

: 1005776-31-7
(E)-ethyl-3-((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl)oxiran-2-yl)acrylates

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 0 ℃; optical yield given as %de;
DOI:10.1590/S0103-50532012000200022

Reference yield:

: 146986-42-7
((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl) oxiran-2-yl)methanol

: 1005776-31-7
(E)-ethyl-3-((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl)oxiran-2-yl)acrylates

Guidance literature:: Multi-step reaction with 2 steps

1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / -78 °C

2: sodium hydride / tetrahydrofuran / 0 °C

With oxalyl dichloride; sodium hydride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; dichloromethane; 1: Swern oxidation / 2: Horner-Wadsworth-Emmons olefination;
DOI:10.1590/S0103-50532012000200022