2-(4-benzyloxy-3,3-dimethyl-cyclopent-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Base Information

Chemical Name:2-(4-benzyloxy-3,3-dimethyl-cyclopent-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane
CAS No.:915377-91-2
Molecular Formula:C₂₀H₂₉BO₃
Molecular Weight:328.259
Hs Code.:

Synonyms:2-(4-benzyloxy-3,3-dimethyl-cyclopent-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

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Chemical Property of 2-(4-benzyloxy-3,3-dimethyl-cyclopent-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

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Technology Process of 2-(4-benzyloxy-3,3-dimethyl-cyclopent-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

There total 1 articles about 2-(4-benzyloxy-3,3-dimethyl-cyclopent-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4058-51-9
2,2-dimethyl-3,4-pentadienal

: 915377-91-2
2-(4-benzyloxy-3,3-dimethyl-cyclopent-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:: Multi-step reaction with 2 steps

1: Pd(dba)2; (R)-1,1'-binaphthalenyl-2-yl-bis(3,5-Me₂-phenyl)phosphane / toluene / 90 h / 0 °C

2: Me₃SiOTf / CH₂Cl₂ / 6 h / -78 °C

With trimethylsilyl trifluoromethanesulfonate; (R)-(+)-2,2'-bis[bis(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In dichloromethane; toluene;
DOI:10.1021/ja063934h

Reference yield:

: 915377-91-2
2-(4-benzyloxy-3,3-dimethyl-cyclopent-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

: 5798-75-4
Ethyl 4-bromobenzoate

: 915377-93-4
4-(4-benzyloxy-3,3-dimethyl-cyclopent-1-enyl)-benzoic acid ethyl ester

Guidance literature:: With potassium phosphate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; In water; toluene; at 100 ℃; for 1h;
DOI:10.1021/ja063934h

Reference yield:

: 915377-91-2
2-(4-benzyloxy-3,3-dimethyl-cyclopent-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

: 4-(4-hydroxy-3,3-dimethyl-cyclopentyl)-benzoic acid ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: K₃PO₄ / Pd(OAc)2; 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl / H₂O; toluene / 1 h / 100 °C

2: H₂ / Pd/C / ethanol / 10 h / 65 °C

With potassium phosphate; hydrogen; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; palladium on activated charcoal; In ethanol; water; toluene; 1: Suzuki coupling;
DOI:10.1021/ja063934h