4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]phenylethynyltrimethylsilane

Base Information

• Chemical Name: 4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]phenylethynyltrimethylsilane
• CAS No.: 1097651-35-8
• Molecular Formula: C₁₇H₂₄O₃Si
• Molecular Weight: 304.461
• Mol file: 1097651-35-8.mol

Synonyms:4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]phenylethynyltrimethylsilane

Chemical Property of 4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]phenylethynyltrimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]phenylethynyltrimethylsilane

There total 1 articles about 4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]phenylethynyltrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

4-(4-bromophenyloxymethyl)-2,2-dimethyl-1,3-dioxolane (198275-89-7) + trimethylsilylacetylene (1066-54-2) → 4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]phenylethynyltrimethylsilane (1097651-35-8)

Guidance literature:

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; for 5h; Inert atmosphere; Reflux;

DOI:10.1002/anie.200802021

Reference yield: 81.0%

4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]phenylethynyltrimethylsilane (1097651-35-8) → 4-[(2,2-dimethyl-1,3-dioxolane-4-yl)methoxy]phenylacetylene (1097651-36-9)

Guidance literature:

4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]phenylethynyltrimethylsilane; With potassium hydroxide; In methanol; at 20 ℃; for 3h;

With water; In diethyl ether; at 20 ℃;

DOI:10.1002/anie.200802957

upstream raw materials:

4-(4-bromophenyloxymethyl)-2,2-dimethyl-1,3-dioxolane

trimethylsilylacetylene

Downstream raw materials:

4-[(2,2-dimethyl-1,3-dioxolane-4-yl)methoxy]phenylacetylene