ethyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2,4-di-O-benzyl-1-thio-α-L-rhamnopyranoside

Base Information

• Chemical Name: ethyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2,4-di-O-benzyl-1-thio-α-L-rhamnopyranoside
• CAS No.: 1622317-95-6
• Molecular Formula: C₅₆H₆₂O₉S
• Molecular Weight: 911.169
• Mol file: 1622317-95-6.mol

Synonyms:ethyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2,4-di-O-benzyl-1-thio-α-L-rhamnopyranoside

Chemical Property of ethyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2,4-di-O-benzyl-1-thio-α-L-rhamnopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2,4-di-O-benzyl-1-thio-α-L-rhamnopyranoside

There total 1 articles about ethyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2,4-di-O-benzyl-1-thio-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate (74808-09-6) + ethyl 2,4-di-O-benzoyl-1-thio-α-L-rhamnopyranoside (156626-44-7) → ethyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2,4-di-O-benzyl-1-thio-α-L-rhamnopyranoside (1622317-95-6)

Guidance literature:

With nitrosonium tetrafluoroborate; In diethyl ether; dichloromethane; at -10 ℃; for 0.5h; stereoselective reaction; Inert atmosphere;

DOI:10.1002/ejoc.201402392

Reference yield:

ethyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-2,4-di-O-benzyl-1-thio-α-L-rhamnopyranoside (1622317-95-6) → C54H58O10

Guidance literature:

With N-Bromosuccinimide; In water; acetone; at 20 ℃; for 0.666667h;

DOI:10.1002/ejoc.201402392

upstream raw materials:

2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

ethyl 2,4-di-O-benzoyl-1-thio-α-L-rhamnopyranoside