benzyl 5,6-anhydro-2,3-O-(1-methylethylidene)-β-D-gulofuranoside

Base Information

• Chemical Name: benzyl 5,6-anhydro-2,3-O-(1-methylethylidene)-β-D-gulofuranoside
• CAS No.: 87598-97-8
• Molecular Formula: C₁₆H₂₀O₅
• Molecular Weight: 292.332
• Mol file: 87598-97-8.mol

Synonyms:benzyl 5,6-anhydro-2,3-O-(1-methylethylidene)-β-D-gulofuranoside

Chemical Property of benzyl 5,6-anhydro-2,3-O-(1-methylethylidene)-β-D-gulofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of benzyl 5,6-anhydro-2,3-O-(1-methylethylidene)-β-D-gulofuranoside

There total 1 articles about benzyl 5,6-anhydro-2,3-O-(1-methylethylidene)-β-D-gulofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

(R)-1-((3aR,4R,6R,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-ethane-1,2-diol (74912-02-0) → benzyl 5,6-anhydro-2,3-O-(1-methylethylidene)-β-D-gulofuranoside (87598-97-8)

Guidance literature:

With sodium hydride; N-tosylimidazole; In tetrahydrofuran; 1.) 0 deg C, 15 min, 2.) 0 deg C, 45 min;

DOI:10.1021/jo00174a008

Reference yield: 79.0%

benzyl 5,6-anhydro-2,3-O-(1-methylethylidene)-β-D-gulofuranoside (87598-97-8) → benzyl 6-deoxy-2,3-O-(1-methylethylidene)-β-D-gulofuranoside (87598-98-9)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether;

DOI:10.1021/jo00174a008

upstream raw materials:

(R)-1-((3aR,4R,6R,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-ethane-1,2-diol

Downstream raw materials:

benzyl 6-deoxy-2,3-O-(1-methylethylidene)-β-D-gulofuranoside