(E)-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal

Base Information

Chemical Name:(E)-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal
CAS No.:930573-19-6
Molecular Formula:C₉H₁₄O₃
Molecular Weight:170.208
Hs Code.:

Synonyms:(E)-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal

Suppliers and Price of (E)-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (E)-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (E)-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal

There total 1 articles about (E)-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 29021-98-5
3-(2-methyl-[1,3]dioxolan-2-yl)-propan-1-ol

: 930573-19-6
(E)-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal

Guidance literature:: Multi-step reaction with 4 steps

1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / -78 °C / Inert atmosphere

1.2: 1.25 h / -78 - 20 °C / Inert atmosphere

2.1: dichloromethane / 17 h / 20 °C

3.1: diisobutylaluminium hydride / hexane; dichloromethane / 2 h / -78 °C / Inert atmosphere

4.1: manganese(IV) oxide / dichloromethane / 24 h

With manganese(IV) oxide; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; In hexane; dichloromethane; 2.1: Wittig reaction;
DOI:10.1002/adsc.201100917

Reference yield:

: 930573-19-6
(E)-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal

: 1243634-58-3
(-)-methyl (1R,2R,3S,5S)-3-(benzoyloxy)-1,8-dimethyl-8-azabicyclo[3.2.1]octane-2-carboxylate

Guidance literature:: Multi-step reaction with 8 steps

1: (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine / chloroform / 41 h / 4 °C

2: chloroform / 2 h / 20 °C

3: triethylsilane; triethylamine; palladium dichloride / dichloromethane / 8 h / Inert atmosphere; Reflux

4: hydrogenchloride; water / tetrahydrofuran / 2 h / 20 °C

5: aluminum tri-tert-butoxide / toluene / 68 h / 20 - 150 °C / pressure tube

6: benzene / 24 h / 85 °C

7: palladium 10% on activated carbon; hydrogen / methanol / 24 h / 20 °C / 2585.81 - 3620.13 Torr

8: dmap; triethylamine / dichloromethane / 17 h / 0 - 20 °C

With hydrogenchloride; triethylsilane; dmap; (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; palladium 10% on activated carbon; water; hydrogen; aluminum tri-tert-butoxide; triethylamine; palladium dichloride; In tetrahydrofuran; methanol; dichloromethane; chloroform; toluene; benzene; 1: Michael condensation / 2: Wittig reaction / 6: sealed pressure tube;
DOI:10.1002/adsc.201100917

Reference yield:

: 930573-19-6
(E)-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal

: 1374584-68-5
(S,E)-methyl 5-(((benzyloxy)carbonyl)((tert-butyldimethylsilyl)oxy)amino)-7-(2-methyl-1,3-dioxolan-2-yl)hept-2-enoate

Guidance literature:: Multi-step reaction with 2 steps

1: (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine / chloroform / 41 h / 4 °C

2: chloroform / 2 h / 20 °C

With (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; In chloroform; 1: Michael condensation / 2: Wittig reaction;
DOI:10.1002/adsc.201100917