10-(4-(hexyloxy)phenyl)-7-(10-(4-(hexyloxy)phenyl)-3-(10-(4-(hexyloxy)phenyl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)-10H-phenothiazine-3-carbaldehyde

Base Information

• Chemical Name: 10-(4-(hexyloxy)phenyl)-7-(10-(4-(hexyloxy)phenyl)-3-(10-(4-(hexyloxy)phenyl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)-10H-phenothiazine-3-carbaldehyde
• CAS No.: 1403613-87-5
• Molecular Formula: C₇₃H₇₁N₃O₄S₃
• Molecular Weight: 1150.58
• Mol file: 1403613-87-5.mol

Synonyms:10-(4-(hexyloxy)phenyl)-7-(10-(4-(hexyloxy)phenyl)-3-(10-(4-(hexyloxy)phenyl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)-10H-phenothiazine-3-carbaldehyde

Chemical Property of 10-(4-(hexyloxy)phenyl)-7-(10-(4-(hexyloxy)phenyl)-3-(10-(4-(hexyloxy)phenyl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)-10H-phenothiazine-3-carbaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-(4-(hexyloxy)phenyl)-7-(10-(4-(hexyloxy)phenyl)-3-(10-(4-(hexyloxy)phenyl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)-10H-phenothiazine-3-carbaldehyde

There total 4 articles about 10-(4-(hexyloxy)phenyl)-7-(10-(4-(hexyloxy)phenyl)-3-(10-(4-(hexyloxy)phenyl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)-10H-phenothiazine-3-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C48H49BN2O4S2 + 7-bromo-10-(4-(hexyloxy)phenyl)-10H-phenothiazine-3-carbaldehyde (1403613-86-4) → 10-(4-(hexyloxy)phenyl)-7-(10-(4-(hexyloxy)phenyl)-3-(10-(4-(hexyloxy)phenyl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)-10H-phenothiazine-3-carbaldehyde (1403613-87-5)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; water; toluene; at 60 ℃; for 12h; Inert atmosphere;

DOI:10.1039/c2jm35556f

Reference yield:

{10-[4-(hexyloxy)phenyl]-10H-phenothiazin-3-yl}boronic acid → 10-(4-(hexyloxy)phenyl)-7-(10-(4-(hexyloxy)phenyl)-3-(10-(4-(hexyloxy)phenyl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)-10H-phenothiazine-3-carbaldehyde (1403613-87-5)

Guidance literature:

Multi-step reaction with 4 steps

1.1: potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran; water; toluene / 12 h / 60 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 - 0 °C / Inert atmosphere

2.2: -78 - 20 °C / Inert atmosphere

3.1: hydrogenchloride; water / tetrahydrofuran; hexane / 1 h / 20 °C / Inert atmosphere

4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran; water; toluene / 12 h / 60 °C / Inert atmosphere

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; water; potassium carbonate; In tetrahydrofuran; hexane; water; toluene; 1.1: |Suzuki-Miyaura Coupling / 4.1: |Suzuki-Miyaura Coupling;

DOI:10.1039/c2jm35556f

Reference yield:

3-bromo-10-[4-(hexyloxy)phenyl]-10H-phenothiazine (1403613-81-9) → 10-(4-(hexyloxy)phenyl)-7-(10-(4-(hexyloxy)phenyl)-3-(10-(4-(hexyloxy)phenyl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)-10H-phenothiazine-3-carbaldehyde (1403613-87-5)

Guidance literature:

Multi-step reaction with 6 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 - 0 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: hydrogenchloride; water / tetrahydrofuran; hexane / 1 h / 20 °C / Inert atmosphere

3.1: potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran; water; toluene / 12 h / 60 °C / Inert atmosphere

4.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 - 0 °C / Inert atmosphere

4.2: -78 - 20 °C / Inert atmosphere

5.1: hydrogenchloride; water / tetrahydrofuran; hexane / 1 h / 20 °C / Inert atmosphere

6.1: potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran; water; toluene / 12 h / 60 °C / Inert atmosphere

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; water; potassium carbonate; In tetrahydrofuran; hexane; water; toluene; 3.1: |Suzuki-Miyaura Coupling / 6.1: |Suzuki-Miyaura Coupling;

DOI:10.1039/c2jm35556f

upstream raw materials:

3-bromo-10-[4-(hexyloxy)phenyl]-10H-phenothiazine

7-bromo-10-(4-(hexyloxy)phenyl)-10H-phenothiazine-3-carbaldehyde

Downstream raw materials:

(E)-2-cyano-3-(10-(4-(hexyloxy)phenyl)-3-(10-(4-(hexyloxy)-phenyl)-3-(10-(4-(hexyloxy)phenyl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)-10H-phenothiazin-7-yl)acrylic acid