10-[4-ethynylphenyl]-17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II)

Base Information

Chemical Name:10-[4-ethynylphenyl]-17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II)
CAS No.:525594-12-1
Molecular Formula:C₃₇H₂₆N₄OZn
Molecular Weight:608.03
Hs Code.:

Synonyms:10-[4-ethynylphenyl]-17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II)

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Chemical Property of 10-[4-ethynylphenyl]-17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II)

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Technology Process of 10-[4-ethynylphenyl]-17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II)

There total 1 articles about 10-[4-ethynylphenyl]-17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 378751-09-8
10-[4-ethynylphenyl]-17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II)

: 525594-12-1
10-[4-ethynylphenyl]-17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II)

Guidance literature:: With basic alumina; air; 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; In toluene; soln. zinc chorin (toluene), basic alumina; stirring for 16 h at 60°C in air; concd.; solid dissolved (toluene); 2,3-dichloro-5,6-dicyano-1,4-benzoquinone added; stirred for 5 min; triethyamine; Taniguchi, M. J. Org. Chem. 2002, 67, 7329-7342; vac.; chromy. (silica, CH2Cl2);;
DOI:10.1021/jp0269423

Reference yield: 51.0%

: 525594-12-1
10-[4-ethynylphenyl]-17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II)

: 359857-37-7
N-(4-Iodophenyl)-N'-(2,5-di-tert-butylphenyl)-3,4,9,10-perylenebis(dicarboximide)

: 525594-18-7
N-(4-[2-[4-[17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II)-10-yl]phenyl]ethnyl]phenyl)-N'(2,5-di-tert-butylphenyl)-3,4,9,10-perylene-bis(dicarboximide)

Guidance literature:: With tri-o-tolylphosphine; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In triethylamine; toluene; ethynyphenyl-substituted Zn oxochlorine, iodo-substituted perylene, Pd2(dba)3, P(o-tol)3 placed in flask filled with Ar; toluene/triethylamine added; mixt. heated to 35°C; after 4 h identical batch of catalystadded; reaction for 7 h; cooled to 25°C; filtered; washed (CHCl3); filtrate concd. to afford solid; chromy. (silica, CH2Cl2-CH2Cl2/MeOH), preparative SEC (THF); chromy. (silica column, CHCl3); washed MeOH;;
DOI:10.1021/jp0269423