(1'E)-phenyl 3,4,6-tri-O-benzyl-2-O-[diisopropyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranosyl sulphoxide

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Chemical Name:(1'E)-phenyl 3,4,6-tri-O-benzyl-2-O-[diisopropyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranosyl sulphoxide
CAS No.:767340-80-7
Molecular Formula:C₄₅H₆₀O₆SSi₂
Molecular Weight:785.205
Hs Code.:

Synonyms:(1'E)-phenyl 3,4,6-tri-O-benzyl-2-O-[diisopropyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranosyl sulphoxide

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Chemical Property of (1'E)-phenyl 3,4,6-tri-O-benzyl-2-O-[diisopropyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranosyl sulphoxide

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Technology Process of (1'E)-phenyl 3,4,6-tri-O-benzyl-2-O-[diisopropyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranosyl sulphoxide

There total 7 articles about (1'E)-phenyl 3,4,6-tri-O-benzyl-2-O-[diisopropyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranosyl sulphoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 767340-81-8
(1'E)-phenyl 3,4,6-tri-O-benzyl-2-O-[diisopropyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-1-thio-α-D-mannopyranoside

: 767340-80-7
(1'E)-phenyl 3,4,6-tri-O-benzyl-2-O-[diisopropyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranosyl sulphoxide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 ℃; for 0.75h;
DOI:10.1021/jo049061w

Reference yield:

: 767340-67-0
(E)-1-(Chloro-diisopropyl-silanyl)-3-trimethylsilanyl-propene

: 767340-80-7
(1'E)-phenyl 3,4,6-tri-O-benzyl-2-O-[diisopropyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranosyl sulphoxide

Guidance literature:: Multi-step reaction with 2 steps

1: 76 percent / imidazole; DMAP / CH₂Cl₂ / 36 h / 20 °C

2: 88 percent / m-CPBA / CH₂Cl₂ / 0.75 h / -78 °C

With 1H-imidazole; dmap; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jo049061w

Reference yield:

: 767340-66-9
{(E)-3-[(diethylamino)diisopropylsilyl]allyl}trimethylsilane

: 767340-80-7
(1'E)-phenyl 3,4,6-tri-O-benzyl-2-O-[diisopropyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranosyl sulphoxide

Guidance literature:: Multi-step reaction with 3 steps

1: CH₂Cl₂ / 24 h / 20 °C

2: 76 percent / imidazole; DMAP / CH₂Cl₂ / 36 h / 20 °C

3: 88 percent / m-CPBA / CH₂Cl₂ / 0.75 h / -78 °C

With 1H-imidazole; dmap; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jo049061w