1-stearoyl-2-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol

Base Information

• Chemical Name: 1-stearoyl-2-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol
• CAS No.: 81093-29-0
• Molecular Formula: C₄₂H₆₆O₁₃
• Molecular Weight: 778.978

Synonyms:1-stearoyl-2-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol

Chemical Property of 1-stearoyl-2-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol

Chemical Property:

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Technology Process of 1-stearoyl-2-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol

There total 1 articles about 1-stearoyl-2-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

1-stearoyl-2-O-benzyl-rac-glycerol (18679-03-3) + 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (572-09-8) → 2-O-benzyl-3-stearoyl-1-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol (81093-30-3) + 1-stearoyl-2-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol (81093-29-0)

Guidance literature:

With calcium sulfate; silver(l) oxide; In chloroform; at 20 ℃; 1.) 1 h; 2.) 3 h, then overnight;

Reference yield:

benzyl chloride (100-44-7) + 1-stearoyl-2-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol (81093-29-0) → 1,2-di-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-sn-glycerol (81093-32-5)

Guidance literature:

With potassium hydroxide; at 80 - 90 ℃; for 5h;

upstream raw materials:

1-stearoyl-2-O-benzyl-rac-glycerol

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

Downstream raw materials:

1,2-di-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-sn-glycerol

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