Technology Process of C41H72O9Si3
There total 8 articles about C41H72O9Si3 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C40H70O9Si3;
With
caesium carbonate;
In
acetonitrile;
at 20 ℃;
for 0.166667h;
Inert atmosphere;
dimethyl sulfate;
In
acetonitrile;
for 5h;
Overall yield = 69 %;
Inert atmosphere;
DOI:10.1021/ja501460j
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium carbonate; water / 1 h / 20 °C
2.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 1 h / 20 - 80 °C / Inert atmosphere
3.1: caesium carbonate / acetonitrile / 0.17 h / 20 °C / Inert atmosphere
3.2: 5 h / Inert atmosphere
With
water; potassium carbonate; caesium carbonate; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
dimethyl sulfoxide; acetonitrile;
DOI:10.1021/ja501460j
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: lithium hydroxide; water / methanol; tetrahydrofuran-d8 / 20 °C
2.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 2 h / 20 - 63 °C / Inert atmosphere
3.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran; toluene / 3 h / 20 - 60 °C / Inert atmosphere
4.1: potassium carbonate; water / 1 h / 20 °C
5.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 1 h / 20 - 80 °C / Inert atmosphere
6.1: caesium carbonate / acetonitrile / 0.17 h / 20 °C / Inert atmosphere
6.2: 5 h / Inert atmosphere
With
di-isopropyl azodicarboxylate; water; potassium carbonate; caesium carbonate; triphenylphosphine; lithium hydroxide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
tetrahydrofuran; methanol; tetrahydrofuran-d8; dimethyl sulfoxide; toluene; acetonitrile;
DOI:10.1021/ja501460j
