(5S,6S)-2,6-dimethyl-6-(cis-3-iodo-2-propenyl)-5-isopropyl-2-cyclohexenone

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Chemical Name:(5S,6S)-2,6-dimethyl-6-(cis-3-iodo-2-propenyl)-5-isopropyl-2-cyclohexenone
CAS No.:308796-84-1
Molecular Formula:C₁₄H₂₁IO
Molecular Weight:332.225
Hs Code.:

Synonyms:(5S,6S)-2,6-dimethyl-6-(cis-3-iodo-2-propenyl)-5-isopropyl-2-cyclohexenone

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Chemical Property of (5S,6S)-2,6-dimethyl-6-(cis-3-iodo-2-propenyl)-5-isopropyl-2-cyclohexenone

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Technology Process of (5S,6S)-2,6-dimethyl-6-(cis-3-iodo-2-propenyl)-5-isopropyl-2-cyclohexenone

There total 3 articles about (5S,6S)-2,6-dimethyl-6-(cis-3-iodo-2-propenyl)-5-isopropyl-2-cyclohexenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 142389-35-3
(Z)-1-iodo-3-methanesulfonyloxy-1-propene

: 308796-89-6
(5R,6S)-2,6-dimethyl-5-isopropyl-2-cyclohexen-1-one

: 308796-84-1
(5S,6S)-2,6-dimethyl-6-(cis-3-iodo-2-propenyl)-5-isopropyl-2-cyclohexenone

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide; In tetrahydrofuran; at -40 - 25 ℃; for 22h;
DOI:10.1016/S0040-4020(00)00658-X

Reference yield:

: 33375-08-5
(R)-5-isopropyl-2-methylcyclohex-2-enone

: 308796-84-1
(5S,6S)-2,6-dimethyl-6-(cis-3-iodo-2-propenyl)-5-isopropyl-2-cyclohexenone

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / diisopropylamine; n-BuLi / tetrahydrofuran; hexane / 3 h / -78 - 25 °C

2: 76 percent / LDA; HMPA / tetrahydrofuran / 22 h / -40 - 25 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; hexane; 1: Methylation / 2: Substitution;
DOI:10.1016/S0040-4020(00)00658-X

Reference yield:

: 6485-40-1,2244-16-8
(R)-Carvone

: 308796-84-1
(5S,6S)-2,6-dimethyl-6-(cis-3-iodo-2-propenyl)-5-isopropyl-2-cyclohexenone

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / H₂; RhCl(PPh₃)3 / benzene

2: 85 percent / diisopropylamine; n-BuLi / tetrahydrofuran; hexane / 3 h / -78 - 25 °C

3: 76 percent / LDA; HMPA / tetrahydrofuran / 22 h / -40 - 25 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; RhCl(PPh₃)3; hydrogen; diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; hexane; benzene; 1: Reduction / 2: Methylation / 3: Substitution;
DOI:10.1016/S0040-4020(00)00658-X