(3-Glycidoxypropyl)trimethoxysilane

Base Information

• Chemical Name: (3-Glycidoxypropyl)trimethoxysilane
• CAS No.: 2530-83-8
• Deprecated CAS: 108727-79-3,120026-01-9,138590-36-0,163035-07-2,26348-10-7,51938-40-0,53029-18-8,65323-93-5,88385-40-4,225795-63-1,346694-79-9,66796-19-8,834889-14-4,852245-94-4,625115-01-7,1258965-22-8,52254-18-9,597543-71-0,861807-90-1,1370605-09-6,2170716-79-5,120026-01-9,1258965-22-8,163035-07-2,225795-63-1,26348-10-7,346694-79-9,51938-40-0,52254-18-9,53029-18-8,597543-71-0,625115-01-7,65323-93-5,66796-19-8,834889-14-4,852245-94-4,861807-90-1,88385-40-4
• Molecular Formula: C9H20O5Si
• Molecular Weight: 236.34
• Hs Code.: 29310095
• European Community (EC) Number: 219-784-2,247-194-5,874-870-2,884-834-8
• NSC Number: 93590
• UNII: 5K9X9X899R
• DSSTox Substance ID: DTXSID5027489
• Nikkaji Number: J48.152A
• Wikidata: Q27262482
• ChEMBL ID: CHEMBL2140162
• Mol file: 2530-83-8.mol

Synonyms:gamma-glycidoxypropyltrimethoxysilane

Chemical Property of (3-Glycidoxypropyl)trimethoxysilane

Chemical Property:

• Appearance/Colour: Colorless transparent liquid
• Vapor Pressure: 0.00213mmHg at 25°C
• Melting Point: -50 °C
• Refractive Index: n20/D 1.429(lit.)
• Boiling Point: 299.4 °C at 760 mmHg
• Flash Point: 81.9 °C
• PSA: 49.45000
• Density: 1.047 g/cm³
• LogP: 0.67000
• Storage Temp.: 2-8°C
• Sensitive.: Moisture Sensitive
• Solubility.: Acetonitrile (Slightly), Chloroform
• Water Solubility.: Miscible with alcohols, ketones and aliphatic or aromatic hydrocarbons. Immiscible with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 9
• Exact Mass: 236.10800027
• Heavy Atom Count: 15
• Complexity: 166

Purity/Quality:

99%, ^*data from raw suppliers

3-Glycidoxypropyltrimethoxysilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn,Xi
• Statements: 36/38-21-52-41
• Safety Statements: 28A-26-36/37/39-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: UVCB,Plastics & Rubber -> Glycidyl Ethers
• Canonical SMILES: CO[Si](CCCOCC1CO1)(OC)OC
• Uses: 3-Glycidoxypropyltrimethoxysilane is an epoxy-functional silane, it is a clear, light straw liquid. 3-Glycidoxypropyltrimethoxysilane may be used as a coupling agent in polysulfide and polyurethane caulks and sealants, in mineral-filled or glass-reinforced thermosets and thermoplastics, and in glass roving size-binders. It is particularly employed as an adhesion-promoting additive in waterborne systems, e.g. improving the adhesion of acrylic latex sealants. Applications: 3-Glycidoxypropyltrimethoxysilane may improve dry and wet strength in cured composites reinforced with glass fiber rovings Enhance wet electrical properties of epoxy-based encapsulate and packaging materials. Eliminate the need for a separate primer in polysulfide and urethane sealants. Improve adhesion in waterborne acrylic sealants and in urethane and epoxy coatings. Pre-treatment of carbon steel with 3-(Glycidoxypropyl)trimet?hoxysilane enhances the dry and wet adhesion while reducing the cathotic disbondment rate of an epoxy coating (3-Glycidoxypropyl)trimethoxysilane is used in the production of carbon steel and its pre treatment favors the dry and wet adhesion of epoxy coating. It is also used to prepare epoxy-functionalized silica nanoparticles, which gives a reactive surface for one-step and high-density protein immobilization. It serves as a coupling agent and adhesion promoter.

Technology Process of (3-Glycidoxypropyl)trimethoxysilane

There total 4 articles about (3-Glycidoxypropyl)trimethoxysilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

Allyl glycidyl ether (106-92-3,25639-25-2,90907-93-0) + trimethoxysilane (2487-90-3) → 3-glycidoxypropyltrimethoxysilane (2530-83-8,88385-40-4)

Guidance literature:

trimethoxysilane; C₁₃H₂₈N₂OPtSi₂; In xylene; for 0.0833333h; Inert atmosphere; Reflux;

Allyl glycidyl ether; In xylene; for 2h; Product distribution / selectivity; Reflux;

Reference yield:

Allyl glycidyl ether (106-92-3,25639-25-2,90907-93-0) + trimethoxysilane (2487-90-3) → 3-glycidoxypropyltrimethoxysilane (2530-83-8,88385-40-4) + (Z)-1-propenyl glycidyl ether

Guidance literature:

With acetic acid; platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; at 160 ℃; Product distribution / selectivity; tube reactor;

Reference yield:

Allyl glycidyl ether (106-92-3,25639-25-2,90907-93-0) + trimethoxysilane (2487-90-3) → 3-glycidoxypropyltrimethoxysilane (2530-83-8,88385-40-4) + (Z)-1-propenyl glycidyl ether + (E)-1-propenyl glycidyl ether

Guidance literature:

platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; at 160 ℃; Product distribution / selectivity; tube reactor;

upstream raw materials:

Allyl glycidyl ether

trimethoxysilane

Downstream raw materials:

4-((3-(trimethoxysilyl)propoxy)methyl)-1,3-dioxolan-2-one

C₁₁H₂₀N₂O₄Si

C₁₂H₂₄N₂O₅Si

C₂₃H₄₄N₄O₉Si₂

Refernces

• 1、 Buslov, Ivan,Song, Fang,Hu, Xile. "An Easily Accessed Nickel Nanoparticle Catalyst for Alkene Hydrosilylation with Tertiary Silanes". supporting information. p. 12295 - 12299. Retrieved 2016/10/13.
• 2、 -. "COSMETIC TREATMENT METHOD COMPRISING THE APPLICATION OF A COATING BASED ON AN AEROGEL COMPOSITION OF LOW BULK DENSITY". Paragraph 0069. . Retrieved 2014/02/15.