(E)-1-(2-carbomethoxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

Base Information

• Chemical Name: (E)-1-(2-carbomethoxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene
• CAS No.: 77837-75-3
• Molecular Formula: C₂₄H₃₀O₂
• Molecular Weight: 350.501

Synonyms:(E)-1-(2-carbomethoxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

Chemical Property of (E)-1-(2-carbomethoxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

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Technology Process of (E)-1-(2-carbomethoxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

There total 2 articles about (E)-1-(2-carbomethoxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl o-formylbenzoate (4122-56-9) + [(2E,4E)-3-methyl-5-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-2,4-dienyl]triphenylphosphonium chloride (53282-28-3) → 2-[(1Z,3E,5E)-4-Methyl-6-(2,6,6-trimethyl-cyclohex-1-enyl)-hexa-1,3,5-trienyl]-benzoic acid methyl ester (77837-76-4) + (E)-1-(2-carbomethoxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene (77837-75-3)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; tert-butyl alcohol; for 22h; Ambient temperature;

DOI:10.1021/jm00137a019

Reference yield:

methyl o-formylbenzoate (4122-56-9) + [(2E,4E)-3-methyl-5-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-2,4-dienyl]triphenylphosphonium chloride (53282-28-3) → (E)-1-(2-carbomethoxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene (77837-75-3)

Guidance literature:

With potassium tert-butylate; iodine; Multistep reaction; 1.) t-BuOH, THF, RT, 22 h, 2.) ether, toluene, irrad., 1.75 h;

DOI:10.1021/jm00137a019

Reference yield: 67.0%

(E)-1-(2-carbomethoxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene (77837-75-3) → (E)-1-(2-carboxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene (77837-58-2)

Guidance literature:

With potassium hydroxide; In ethanol; water; at 80 ℃; for 0.166667h;

DOI:10.1021/jm00137a019

upstream raw materials:

methyl o-formylbenzoate

[(2E,4E)-3-methyl-5-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-2,4-dienyl]triphenylphosphonium chloride

Downstream raw materials:

(E)-1-(2-carboxyphenyl)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

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