Technology Process of 4-allyl-3,4,5-trimethoxycyclohexa-2,5-dienone
There total 3 articles about 4-allyl-3,4,5-trimethoxycyclohexa-2,5-dienone which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
4-allyl-4-hydroxy-3,5-dimethoxycyclohexa-2,5-dienone;
With
tetrabutylammomium bromide; sodium hydroxide;
In
water; toluene;
at 20 ℃;
for 0.166667h;
dimethyl sulfate;
In
water; toluene;
for 6h;
DOI:10.2174/157017811795371368
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: titanium tetrachloride / dichloromethane / 0.27 h / -78 °C / Inert atmosphere
1.2: 0.25 h / -50 °C / Inert atmosphere
1.3: 20 °C / Inert atmosphere
2.1: tetrabutylammomium bromide; sodium hydroxide / water; toluene / 0.17 h / 20 °C
2.2: 6 h
With
tetrabutylammomium bromide; titanium tetrachloride; sodium hydroxide;
In
dichloromethane; water; toluene;
1.1: Sakurai reaction / 1.2: Sakurai reaction / 1.3: Sakurai reaction;
DOI:10.2174/157017811795371368
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: dihydrogen peroxide; acetic acid; potassium ferrocyanide / 2 h / 20 °C
2.1: titanium tetrachloride / dichloromethane / 0.27 h / -78 °C / Inert atmosphere
2.2: 0.25 h / -50 °C / Inert atmosphere
2.3: 20 °C / Inert atmosphere
3.1: tetrabutylammomium bromide; sodium hydroxide / water; toluene / 0.17 h / 20 °C
3.2: 6 h
With
tetrabutylammomium bromide; dihydrogen peroxide; titanium tetrachloride; acetic acid; sodium hydroxide; potassium ferrocyanide;
In
dichloromethane; water; toluene;
2.1: Sakurai reaction / 2.2: Sakurai reaction / 2.3: Sakurai reaction;
DOI:10.2174/157017811795371368
