Technology Process of C59H52Cl2F2N2O23
There total 12 articles about C59H52Cl2F2N2O23 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C44H27Cl2F2N2O13(5-)*5K(1+);
With
hydrogenchloride;
In
water;
pH=1.5;
acetoxymethyl bromide;
With
N-ethyl-N,N-diisopropylamine;
In
N,N-dimethyl-formamide;
at 20 ℃;
for 2h;
- Guidance literature:
-
Multi-step reaction with 11 steps
1.1: Selectfluor / acetonitrile / 3 h / 20 °C
2.1: zinc; acetic acid
3.1: SEC-BUTYLAMINE; sulfuryl dichloride / toluene / 3 h / 66 °C
4.1: potassium carbonate / acetonitrile / 2 h / Reflux
5.1: lithium aluminium tetrahydride / diethyl ether / 0.5 h
6.1: pyridinium chlorochromate / dichloromethane / 2 h / 20 °C
7.1: 3-chloro-benzenecarboperoxoic acid; potassium hydroxide / benzene / 24 h / 70 °C
8.1: boron tribromide / dichloromethane / 3 h
8.2: Cooling with ice
9.1: methanesulfonic acid / 1 h / 20 °C
10.1: potassium hydroxide; water / methanol / 0.5 h / 20 °C
11.1: hydrogenchloride / water / pH 1.5
11.2: 2 h / 20 °C
With
hydrogenchloride; lithium aluminium tetrahydride; sulfuryl dichloride; SEC-BUTYLAMINE; methanesulfonic acid; water; boron tribromide; potassium carbonate; acetic acid; Selectfluor; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; potassium hydroxide; zinc;
In
methanol; diethyl ether; dichloromethane; water; toluene; acetonitrile; benzene;
7.1: Baeyer-Villager;
- Guidance literature:
-
Multi-step reaction with 9 steps
1.1: SEC-BUTYLAMINE; sulfuryl dichloride / toluene / 3 h / 66 °C
2.1: potassium carbonate / acetonitrile / 2 h / Reflux
3.1: lithium aluminium tetrahydride / diethyl ether / 0.5 h
4.1: pyridinium chlorochromate / dichloromethane / 2 h / 20 °C
5.1: 3-chloro-benzenecarboperoxoic acid; potassium hydroxide / benzene / 24 h / 70 °C
6.1: boron tribromide / dichloromethane / 3 h
6.2: Cooling with ice
7.1: methanesulfonic acid / 1 h / 20 °C
8.1: potassium hydroxide; water / methanol / 0.5 h / 20 °C
9.1: hydrogenchloride / water / pH 1.5
9.2: 2 h / 20 °C
With
hydrogenchloride; lithium aluminium tetrahydride; sulfuryl dichloride; SEC-BUTYLAMINE; methanesulfonic acid; water; boron tribromide; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; potassium hydroxide;
In
methanol; diethyl ether; dichloromethane; water; toluene; acetonitrile; benzene;
5.1: Baeyer-Villager;