(5,10,15,20-tetra-p-tolylporpyrinato)iron(II)

Base Information

• Chemical Name: (5,10,15,20-tetra-p-tolylporpyrinato)iron(II)
• CAS No.: 19414-68-7
• Molecular Formula: C₄₈H₃₆FeN₄
• Molecular Weight: 724.688
• Mol file: 19414-68-7.mol

Synonyms:(5,10,15,20-tetra-p-tolylporpyrinato)iron(II)

Chemical Property of (5,10,15,20-tetra-p-tolylporpyrinato)iron(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (5,10,15,20-tetra-p-tolylporpyrinato)iron(II)

There total 7 articles about (5,10,15,20-tetra-p-tolylporpyrinato)iron(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

μ-oxo-bis(meso-tetra-p-tolylporphyrin)iron(III) → (5,10,15,20-tetra-p-tolylporpyrinato)iron(II) (19414-68-7)

Guidance literature:

With ethanethiol; In benzene; at 20 ℃; for 48h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.inorgchem.1c02444

Reference yield:

μ-oxo-bis(meso-tetra-p-tolylporphyrin)iron(III) → (5,10,15,20-tetra-p-tolylporpyrinato)iron(II) (19414-68-7)

Guidance literature:

With ethanethiol; In benzene; for 24h;

Reference yield:

(TpCH3PP)Fe(II)(Py)2 (62612-73-1) → (5,10,15,20-tetra-p-tolylporpyrinato)iron(II) (19414-68-7)

Guidance literature:

In neat (no solvent); Fe porphyrinate in Knudsen cell heated to 470 K under vac.; cell evacuated for 3 h, liquid N2 poured in cryostat, cell heated to 520 K to sublime Fe(por) onto KBr or CaF2 substrate; according to K. Nakamoto et al. J.Am. Chem. Soc. 1982, 104, 3744-3745; UV/Vis;

DOI:10.1002/anie.200502409

upstream raw materials:

(TpCH₃PP)Fe(II)(Py)2

meso-tetra-p-tolylporphyrinatobis(piperidine)iron(II)

(tetrakis(p-methylphenyl)porphyrin)Fe(C₆H₅)

styrene

Downstream raw materials:

meso-tetra-p-tolylporphyrinato(η1-nitrito)iron(III)

meso-tetra-p-tolylporphyrinato(η2-nitrato)iron(III)

meso-tetra-p-tolylporphyrinato(η1-[(15)N]nitrito)iron(III)

{tetra-p-tolylporphyrin iron(III)}2(2,6-dimethyl-para-benzoquinone)