p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Base Information

Chemical Name:p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside
CAS No.:858127-26-1
Molecular Formula:C₇₆H₇₉N₃O₁₈
Molecular Weight:1322.47
Hs Code.:

p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Synonyms:p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Suppliers and Price of p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

There total 6 articles about p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 858127-20-5
2,2,2-Trifluoro-N-phenyl-acetimidic acid (2S,3R,4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-methoxycarbonyloxy-tetrahydro-pyran-2-yl ester

: 858127-25-0
(2S,4aR,6S,7R,8R,8aR)-7-Azido-6-[(2R,3S,4S,5R,6S)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-(4-methoxy-phenoxy)-tetrahydro-pyran-4-yloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

: 858127-26-1
p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Guidance literature:: With 5A molecular sieve; In cyclohexane; 1,2-dichloro-ethane; at 20 ℃;
DOI:10.1021/jo050301x

Reference yield:

: Acetic acid (2R,3R,4R,5R)-3-acetoxy-2-acetoxymethyl-5-azido-6-(2,2,2-trifluoro-N-phenyl-acetimidoyloxy)-tetrahydro-pyran-4-yl ester

: 858127-26-1
p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 70 percent / 4 Angstroem AW 300 molecular sieves; Yb(OTf)3 / acetonitrile / 0 - 20 °C

2: aq. NH₄OH / methanol / 3 h / 20 °C

3: 152 mg / camphorsulfonic acid / acetonitrile / 3 h / 70 °C

4: 75 percent / 5 Angstroem AW molecular sieves / 1,2-dichloro-ethane; cyclohexane / 20 °C

With ammonium hydroxide; 4 A molecular sieve; 5A molecular sieve; camphor-10-sulfonic acid; ytterbium(III) triflate; In methanol; cyclohexane; 1,2-dichloro-ethane; acetonitrile;
DOI:10.1021/jo050301x

Reference yield:

: Carbonic acid (3R,4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-hydroxy-tetrahydro-pyran-3-yl ester methyl ester

: 858127-26-1
p-methoxyphenyl 3,4,6-tri-O-benzyl-2-O-methoxycarbonyl-β-D-galactopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-azido-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 658 mg / DIPEA / CH₂Cl₂ / 36 h / 20 °C

2: 75 percent / 5 Angstroem AW molecular sieves / 1,2-dichloro-ethane; cyclohexane / 20 °C

With 5A molecular sieve; N-ethyl-N,N-diisopropylamine; In dichloromethane; cyclohexane; 1,2-dichloro-ethane;
DOI:10.1021/jo050301x