(3aR,8S,19aR,Z)-13-methoxy-4-((4-methoxybenzyl)oxy)-11-(methoxymethoxy)-2,2,8-trimethyl-7,8,19,19a-tetrahydro-3aH-dibenzo[c,e][1,3] dioxolo[4,5-h][1]oxacyclotetradecen-10(4H)-one

Base Information

Chemical Name:(3aR,8S,19aR,Z)-13-methoxy-4-((4-methoxybenzyl)oxy)-11-(methoxymethoxy)-2,2,8-trimethyl-7,8,19,19a-tetrahydro-3aH-dibenzo[c,e][1,3] dioxolo[4,5-h][1]oxacyclotetradecen-10(4H)-one
CAS No.:1606132-43-7
Molecular Formula:C₃₅H₄₀O₉
Molecular Weight:604.697
Hs Code.:

(3aR,8S,19aR,Z)-13-methoxy-4-((4-methoxybenzyl)oxy)-11-(methoxymethoxy)-2,2,8-trimethyl-7,8,19,19a-tetrahydro-3aH-dibenzo[c,e][1,3] dioxolo[4,5-h][1]oxacyclotetradecen-10(4H)-one

Synonyms:(3aR,8S,19aR,Z)-13-methoxy-4-((4-methoxybenzyl)oxy)-11-(methoxymethoxy)-2,2,8-trimethyl-7,8,19,19a-tetrahydro-3aH-dibenzo[c,e][1,3] dioxolo[4,5-h][1]oxacyclotetradecen-10(4H)-one

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Chemical Property of (3aR,8S,19aR,Z)-13-methoxy-4-((4-methoxybenzyl)oxy)-11-(methoxymethoxy)-2,2,8-trimethyl-7,8,19,19a-tetrahydro-3aH-dibenzo[c,e][1,3] dioxolo[4,5-h][1]oxacyclotetradecen-10(4H)-one

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Technology Process of (3aR,8S,19aR,Z)-13-methoxy-4-((4-methoxybenzyl)oxy)-11-(methoxymethoxy)-2,2,8-trimethyl-7,8,19,19a-tetrahydro-3aH-dibenzo[c,e][1,3] dioxolo[4,5-h][1]oxacyclotetradecen-10(4H)-one

There total 11 articles about (3aR,8S,19aR,Z)-13-methoxy-4-((4-methoxybenzyl)oxy)-11-(methoxymethoxy)-2,2,8-trimethyl-7,8,19,19a-tetrahydro-3aH-dibenzo[c,e][1,3] dioxolo[4,5-h][1]oxacyclotetradecen-10(4H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1606132-47-1
C₃₅H₄₂O₁₀

: 1606132-43-7
(3aR,8S,19aR,Z)-13-methoxy-4-((4-methoxybenzyl)oxy)-11-(methoxymethoxy)-2,2,8-trimethyl-7,8,19,19a-tetrahydro-3aH-dibenzo[c,e][1,3] dioxolo[4,5-h][1]oxacyclotetradecen-10(4H)-one

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In toluene; at 0 - 20 ℃; for 0.5h;

Reference yield:

: 1606132-41-5
methyl 3'-((4R,5R)-5-((5R,Z)-5-hydroxy-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

: 1606132-43-7
(3aR,8S,19aR,Z)-13-methoxy-4-((4-methoxybenzyl)oxy)-11-(methoxymethoxy)-2,2,8-trimethyl-7,8,19,19a-tetrahydro-3aH-dibenzo[c,e][1,3] dioxolo[4,5-h][1]oxacyclotetradecen-10(4H)-one

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydroxide; ethanol / 8 h / 80 °C

2: di-isopropyl azodicarboxylate; triphenylphosphine / toluene / 0.5 h / 0 - 20 °C

With ethanol; di-isopropyl azodicarboxylate; triphenylphosphine; sodium hydroxide; In toluene;

Reference yield:

: 1606132-42-6
C₂₃H₂₆O₈

: 1606132-43-7
(3aR,8S,19aR,Z)-13-methoxy-4-((4-methoxybenzyl)oxy)-11-(methoxymethoxy)-2,2,8-trimethyl-7,8,19,19a-tetrahydro-3aH-dibenzo[c,e][1,3] dioxolo[4,5-h][1]oxacyclotetradecen-10(4H)-one

Guidance literature:: Multi-step reaction with 6 steps

1.1: n-butyllithium / tetrahydrofuran / 1.5 h / -78 °C

1.2: 2 h / -78 °C

2.1: hydrogen; quinoline; rosenmund catalyst / ethyl acetate / 8 h / 20 °C

3.1: sodium hydride / N,N-dimethyl-formamide / 0.5 h / 0 °C

3.2: 6 h / 50 °C

4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 18 h / 20 °C

5.1: sodium hydroxide; ethanol / 8 h / 80 °C

6.1: di-isopropyl azodicarboxylate; triphenylphosphine / toluene / 0.5 h / 0 - 20 °C

With quinoline; n-butyllithium; ethanol; di-isopropyl azodicarboxylate; rosenmund catalyst; tetrabutyl ammonium fluoride; hydrogen; sodium hydride; triphenylphosphine; sodium hydroxide; In tetrahydrofuran; ethyl acetate; N,N-dimethyl-formamide; toluene;