C₅₇H₇₇N₅O₁₁

Base Information

• Chemical Name: C₅₇H₇₇N₅O₁₁
• CAS No.: 1394037-18-3
• Molecular Formula: C₅₇H₇₇N₅O₁₁
• Molecular Weight: 1008.27
• Mol file: 1394037-18-3.mol

Synonyms:C₅₇H₇₇N₅O₁₁

Chemical Property of C₅₇H₇₇N₅O₁₁

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₇H₇₇N₅O₁₁

There total 2 articles about C₅₇H₇₇N₅O₁₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

C56H75N5O11 (1394037-08-1) → C57H77N5O11 (1394037-18-3)

Guidance literature:

With dmap; N-ethyl-N,N-diisopropylamine; In methanol; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1021/ol301869x DOI:10.1021/ol301869x

Reference yield:

28-(tert-butoxycarbonyl)-1,6,17,29-tetrakis(benzyloxy)-7,10,18,21-tetraoxo-6,11,17,22,28-pentaazaoctacosane (284666-57-5) → C57H77N5O11 (1394037-18-3)

Guidance literature:

Multi-step reaction with 3 steps

1: trifluoroacetic acid; sodium hydrogencarbonate / dichloromethane / Inert atmosphere

2: dmap; N-ethyl-N,N-diisopropylamine / dichloromethane / 89 h / 20 °C / Inert atmosphere

3: dmap; N-ethyl-N,N-diisopropylamine / methanol / 3 h / 20 °C / Inert atmosphere

With dmap; sodium hydrogencarbonate; N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; In methanol; dichloromethane;

DOI:10.1021/ol301869x DOI:10.1021/ol301869x

upstream raw materials:

28-(tert-butoxycarbonyl)-1,6,17,29-tetrakis(benzyloxy)-7,10,18,21-tetraoxo-6,11,17,22,28-pentaazaoctacosane

C₅₆H₇₅N₅O₁₁

Refernces

• 1、 Wencewicz, Timothy A.,Oliver, Allen G.,Miller, Marvin J.. "Iron(III)-templated macrolactonization of trihydroxamate siderophores". . p. 4390 - 4393. Retrieved 2013/01/14.