Morpholin-4-yl morpholine-4-carbodithioate

Base Information

• Chemical Name: Morpholin-4-yl morpholine-4-carbodithioate
• CAS No.: 13752-51-7
• Deprecated CAS: 57018-26-5
• Molecular Formula: C9H16N2O2S2
• Molecular Weight: 248.37
• Hs Code.: 2934999090
• European Community (EC) Number: 237-335-9
• UNII: W5DXW9JF2G
• DSSTox Substance ID: DTXSID5021095
• Nikkaji Number: J69.008B
• Wikidata: Q26840937
• Mol file: 13752-51-7.mol

Synonyms:N-oxydiethylenethiocarbamoyl-N-oxydiethylene sulfenamide;OTOS

Chemical Property of Morpholin-4-yl morpholine-4-carbodithioate

Chemical Property:

• Vapor Pressure: 6.45E-06mmHg at 25°C
• Melting Point: 139 °C
• Refractive Index: 1.631
• Boiling Point: 378.1 °C at 760 mmHg
• PKA: 1.08±0.20(Predicted)
• Flash Point: 182.4 °C
• PSA: 82.33000
• Density: 1.34 g/cm³
• LogP: 0.45970
• Water Solubility.: 127mg/L at 20℃
• XLogP3: 0.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 2
• Exact Mass: 248.06532010
• Heavy Atom Count: 15
• Complexity: 216

Purity/Quality:

99.9% ^*data from raw suppliers

OTOS ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1COCCN1C(=S)SN2CCOCC2
• Uses: Acceleratorotos is an accelerator; used in preparation of a Rubber anti-fatigue agent.

Technology Process of Morpholin-4-yl morpholine-4-carbodithioate

There total 2 articles about Morpholin-4-yl morpholine-4-carbodithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

morpholine (110-91-8,99108-56-2) + acetyl-trichloromethyl-disulfane (72087-88-8) → 4-(morpholine-4-carbothioylsulfanyl)-morpholine (13752-51-7)

Guidance literature:

In diethyl ether; Mechanism; further α-chloroalkyd disulfides, <18 deg C;

DOI:10.1016/S0040-4020(01)87479-2

Reference yield:

→ 4-(morpholine-4-carbothioylsulfanyl)-morpholine (13752-51-7)

Guidance literature:

CS2, Morpholin;

DOI:10.1021/jo00410a025

upstream raw materials:

morpholine

acetyl-trichloromethyl-disulfane

Refernces

• 1、 -. "Preparation of thiocarbamylsulfenamides". . . Retrieved 2008/06/13.