dimethylphenylsilylmethyl azide

Base Information

• Chemical Name: dimethylphenylsilylmethyl azide
• CAS No.: 1144111-27-2
• Molecular Formula: C₉H₁₃N₃Si
• Molecular Weight: 191.308
• Mol file: 1144111-27-2.mol

Synonyms:dimethylphenylsilylmethyl azide

Chemical Property of dimethylphenylsilylmethyl azide

Chemical Property:

Purity/Quality:

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Technology Process of dimethylphenylsilylmethyl azide

There total 1 articles about dimethylphenylsilylmethyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

chloromethyldimethylphenylsilane (1833-51-8) → dimethylphenylsilylmethyl azide (1144111-27-2)

Guidance literature:

With sodium azide; potassium iodide; In N,N-dimethyl-formamide; at 80 ℃; for 24h;

DOI:10.1002/ejoc.201403200

Reference yield: 81.0%

dimethylphenylsilylmethyl azide (1144111-27-2) + 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (72824-04-5) → C12H19NSi

Guidance literature:

With C₅₄H₄₄N₂O₄Ru₂; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere; Irradiation;

DOI:10.1002/ejoc.201403200

Reference yield: 80.0%

4,4,5,5-tetramethyl-2-(propa-1,2-dien-1-yl)-1,3,2-dioxaborolane (865350-17-0) + dimethylphenylsilylmethyl azide (1144111-27-2) → C12H17NSi

Guidance literature:

With C₅₄H₄₄N₂O₄Ru₂; In tetrahydrofuran; at 50 ℃; for 3h; Inert atmosphere; Irradiation;

DOI:10.1002/ejoc.201403200

upstream raw materials:

chloromethyldimethylphenylsilane

Downstream raw materials:

[6,6]-(1-N-dimethylphenylsilylmethyl-triazoline)-C₆₀