1-phenyl-2-(benzo[k]-phenanthrid-6-yl)-5-phenyl-3,4-butano-phosphole

Base Information

• Chemical Name: 1-phenyl-2-(benzo[k]-phenanthrid-6-yl)-5-phenyl-3,4-butano-phosphole
• CAS No.: 1016165-11-9
• Molecular Formula: C₃₇H₂₈NP
• Molecular Weight: 517.61
• Mol file: 1016165-11-9.mol

Synonyms:1-phenyl-2-(benzo[k]-phenanthrid-6-yl)-5-phenyl-3,4-butano-phosphole

Chemical Property of 1-phenyl-2-(benzo[k]-phenanthrid-6-yl)-5-phenyl-3,4-butano-phosphole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-phenyl-2-(benzo[k]-phenanthrid-6-yl)-5-phenyl-3,4-butano-phosphole

There total 1 articles about 1-phenyl-2-(benzo[k]-phenanthrid-6-yl)-5-phenyl-3,4-butano-phosphole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

6-(8-phenylocta-1,7-diyn-1-yl)-benzo[k]-phenanthridine (1016165-13-1) + phenyldibromophosphine (1073-47-8) → 1-phenyl-2-(benzo[k]-phenanthrid-6-yl)-5-phenyl-3,4-butano-phosphole (1016165-11-9)

Guidance literature:

6-(8-phenylocta-1,7-diyn-1-yl)-benzo[k]-phenanthridine; With n-butyllithium; zirconocene dichloride; In tetrahydrofuran; hexane; at -78 - 20 ℃;

phenyldibromophosphine; In tetrahydrofuran; hexane; at 20 ℃; for 30h; Further stages.;

DOI:10.1039/b714340k

Reference yield: 99.0%

1-phenyl-2-(benzo[k]-phenanthrid-6-yl)-5-phenyl-3,4-butano-phosphole (1016165-11-9) + [Pd(CH3CN)4](SbF6)2 → [Pd(C17NH10C8H8(C6H5)PC6H5)2](2+)

Guidance literature:

In dichloromethane; Pd:P compd.=1:2 molar ratio;

DOI:10.1039/b714340k

Reference yield: 77.0%

1-phenyl-2-(benzo[k]-phenanthrid-6-yl)-5-phenyl-3,4-butano-phosphole (1016165-11-9) + copper(I) → [Cu(C17NH10C8H8(C6H5)PC6H5)2](1+) (1016165-20-0)

Guidance literature:

In dichloromethane; Cu:P compd.=1:2 molar ratio;

DOI:10.1039/b714340k

upstream raw materials:

6-(8-phenylocta-1,7-diyn-1-yl)-benzo[k]-phenanthridine

phenyldibromophosphine

Downstream raw materials:

[Cu(C₁₇NH₁₀C₈H₈(C₆H₅)PC₆H₅)2]⁽¹⁺⁾