[ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-mesityl-1,2-dithiole-3-thione(-H))]

Base Information

• Chemical Name: [ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-mesityl-1,2-dithiole-3-thione(-H))]
• CAS No.: 1206555-15-8
• Molecular Formula: C₄₉H₄₂OP₂RuS₄
• Molecular Weight: 938.153
• Mol file: 1206555-15-8.mol

Synonyms:[ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-mesityl-1,2-dithiole-3-thione(-H))]

Chemical Property of [ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-mesityl-1,2-dithiole-3-thione(-H))]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-mesityl-1,2-dithiole-3-thione(-H))]

There total 2 articles about [ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-mesityl-1,2-dithiole-3-thione(-H))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + 5-mesityl-4-mercapto-1,2-dithiole-3-thione → [ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-mesityl-1,2-dithiole-3-thione(-H))] (1206555-15-8)

Guidance literature:

With NEt₃; In tetrahydrofuran; THF soln. of C12H12S4 treated with NEt3; Ru complex added, stirred for 72 h; isolated by column chromy. (petroleum/CH2Cl2, 13:7); elem. anal.;

DOI:10.1016/j.ica.2009.09.015

Reference yield: 72.0%

carbon disulfide (75-15-0,12122-00-8) + sulfur (10544-50-0) + (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + 2-ethynyl-1,3,5-trimethylbenzene (769-26-6) → [ruthenium(II)(H)(carbonyl)(triphenylphosphine)2(4-mercapto-5-mesityl-1,2-dithiole-3-thione(-H))] (1206555-15-8)

Guidance literature:

With n-BuLi; In tetrahydrofuran; byproducts: triphenylphosphine sulfide; THF soln. of MesCCH cooled to -78°C, treated with n-BuLi; CS2 andS8 added, THF suspn. of Ru complex added, stirred for 24 h; small amt. of SiO2 added, evapd to dryness, isolated by column chromy. (petroleum/CH2Cl2, 7:3); elem. anal.;

DOI:10.1016/j.ica.2009.09.015

upstream raw materials:

carbon disulfide

sulfur

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

2-ethynyl-1,3,5-trimethylbenzene