Rh₄(CO)9{HC(PPh₂)3}

Base Information

Chemical Name:Rh₄(CO)9{HC(PPh₂)3}
CAS No.:86768-38-9
Molecular Formula:C₄₆H₃₁O₉P₃Rh₄
Molecular Weight:1232.29
Hs Code.:

Rh<sub>4</sub>(CO)9{HC(PPh<sub>2</sub>)3}

Synonyms:Rh₄(CO)9{HC(PPh₂)3}

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Chemical Property of Rh₄(CO)9{HC(PPh₂)3}

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Technology Process of Rh₄(CO)9{HC(PPh₂)3}

There total 1 articles about Rh₄(CO)9{HC(PPh₂)3} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 494804-05-6
dodecacarbonyltetrarhodium⁽⁰⁾

: 28926-65-0
Tris(diphenylphosphino)methan

: 86768-38-9
Rh₄(CO)9{HC(PPh₂)3}

Guidance literature:: In hexane; toluene; A soln. of ligand in toluene was added dropwise for 30 min at 25°C to a rapidly stirred soln. of complex in hexane, stirred for 5-6 h (inert atm.);; crystals were filtered, washed with toluene and hexane, dried in vac., recrystd. from THF-hexane or CH2Cl2-hexane; elem. anal.;;

Reference yield: 90.0%

: 86768-38-9
Rh₄(CO)9{HC(PPh₂)3}

: 86751-33-9
Rh₄(CO)8(((C₆H₅)2P)3CH)((C₆H₅)3P)

Guidance literature:: With triphenylphosphine; In dichloromethane; absence of air; dropwise addn. of PPh3 to Rh-complex (during 15 min), stirring (3 h); crystn. on petroleum ether addn.; elem. anal.;
DOI:10.1016/0022-328X(85)88077-3

Reference yield: 86.0%

: 86768-38-9
Rh₄(CO)9{HC(PPh₂)3}

: 18586-39-5
(trisethoxysilyl)ethyldiphenylphosphine

: 86751-34-0
Rh₄(CO)8(((C₆H₅)2P)3CH)((C₆H₅)2PCH₂CH₂Si(OC₂H₅)3)

Guidance literature:: In tetrahydrofuran; absence of air; dropwise addn. of PPh3 to Rh-complex (during 15 min), stirring (3 h); addn. of heptane, distn. (vac.);
DOI:10.1016/0022-328X(85)88077-3