1-aza-1-(cyclohex-2-en-1-yl)-6,6,-dicarbethoxy-9-dimethylphenylsilyl-1-(4-methylbenzenesulfonyl)nona-3,8-diyne

Base Information

Chemical Name:1-aza-1-(cyclohex-2-en-1-yl)-6,6,-dicarbethoxy-9-dimethylphenylsilyl-1-(4-methylbenzenesulfonyl)nona-3,8-diyne
CAS No.:1187209-70-6
Molecular Formula:C₃₅H₄₃NO₆SSi
Molecular Weight:633.881
Hs Code.:

Synonyms:1-aza-1-(cyclohex-2-en-1-yl)-6,6,-dicarbethoxy-9-dimethylphenylsilyl-1-(4-methylbenzenesulfonyl)nona-3,8-diyne

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Chemical Property of 1-aza-1-(cyclohex-2-en-1-yl)-6,6,-dicarbethoxy-9-dimethylphenylsilyl-1-(4-methylbenzenesulfonyl)nona-3,8-diyne

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Technology Process of 1-aza-1-(cyclohex-2-en-1-yl)-6,6,-dicarbethoxy-9-dimethylphenylsilyl-1-(4-methylbenzenesulfonyl)nona-3,8-diyne

There total 1 articles about 1-aza-1-(cyclohex-2-en-1-yl)-6,6,-dicarbethoxy-9-dimethylphenylsilyl-1-(4-methylbenzenesulfonyl)nona-3,8-diyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1187209-86-4
C₂₇H₃₃NO₆S

: 768-33-2
phenyldimethylsilyl chloride

: 1187209-70-6
1-aza-1-(cyclohex-2-en-1-yl)-6,6,-dicarbethoxy-9-dimethylphenylsilyl-1-(4-methylbenzenesulfonyl)nona-3,8-diyne

Guidance literature:: C₂₇H₃₃NO₆S; With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; Inert atmosphere;

phenyldimethylsilyl chloride; In tetrahydrofuran; at -78 - -40 ℃; Inert atmosphere;
DOI:10.1039/b909781c

Reference yield:

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 1187209-70-6
1-aza-1-(cyclohex-2-en-1-yl)-6,6,-dicarbethoxy-9-dimethylphenylsilyl-1-(4-methylbenzenesulfonyl)nona-3,8-diyne

: diethyl-7-[dimethyl(phenyl)silyl]-2-[(4-methylphenyl)sulfonyl]-6-oxo-2,2a,3,4,5,5a,6,7,8,10-decahydroazuleno[4,5,6-cd]indole-9,9(1H)-dicarboxylate

: diethyl-7-[dimethyl(phenyl)silyl]-2-[(4-methylphenyl)sulfonyl]-6-oxo-2,2a,3,4,5,5a,6,8,10,10c-decahydroazuleno[4,5,6-cd]indole-9,9(1H)-dicarboxylate

Guidance literature:: With di(rhodium)tetracarbonyl dichloride; In 1,1-dichloroethane; 2,2,2-trifluoroethanol; at 60 ℃; for 20h; under 1520.1 Torr; Autoclave;
DOI:10.1039/b909781c

Reference yield:

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 1187209-70-6
1-aza-1-(cyclohex-2-en-1-yl)-6,6,-dicarbethoxy-9-dimethylphenylsilyl-1-(4-methylbenzenesulfonyl)nona-3,8-diyne

: C₃₅H₄₃NO₆SSi

: C₃₅H₄₃NO₆SSi

: diethyl-7-[dimethyl(phenyl)silyl]-2-[(4-methylphenyl)sulfonyl]-6-oxo-2,2a,3,4,5,5a,6,7,8,10-decahydroazuleno[4,5,6-cd]indole-9,9(1H)-dicarboxylate

: diethyl-7-[dimethyl(phenyl)silyl]-2-[(4-methylphenyl)sulfonyl]-6-oxo-2,2a,3,4,5,5a,6,8,10,10c-decahydroazuleno[4,5,6-cd]indole-9,9(1H)-dicarboxylate

Guidance literature:: With di(rhodium)tetracarbonyl dichloride; In 1,1-dichloroethane; at 60 ℃; for 50h; under 760.051 Torr;
DOI:10.1039/b909781c