(^iPrPOCOP)NiH

Base Information

• Chemical Name: (^iPrPOCOP)NiH
• CAS No.: 1108747-39-2
• Molecular Formula: C₁₈H₃₂NiO₂P₂
• Molecular Weight: 401.088
• Mol file: 1108747-39-2.mol

Synonyms:(^iPrPOCOP)NiH

Chemical Property of (^iPrPOCOP)NiH

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (^iPrPOCOP)NiH

There total 6 articles about (^iPrPOCOP)NiH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C26H47BNiO2P2 (1378876-25-5) → (iPrPOCOP)NiH (1108747-39-2) + 9-bora-bicyclo[3.3.1]nonane (280-64-8)

Guidance literature:

In ⁽²⁾H₈-toluene; at 22 ℃; Equilibrium constant;

DOI:10.1021/ic300587b

Reference yield:

[2,6-(iPr2PO)2C6H3]Ni(BH4) (1378876-20-0) + triethylamine (121-44-8) → triethylamine-borane (1722-26-5) + (iPrPOCOP)NiH (1108747-39-2)

Guidance literature:

In benzene-d6; at 60 ℃; for 24h;

DOI:10.1021/ic300587b

Reference yield:

C26H36(2)HF3NiO3P2 → (iPrPOCOP)NiH (1108747-39-2) + 4-(trifluoromethyl)benzaldehyde-α-d1

Guidance literature:

at 50 ℃; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/acs.organomet.8b00888

upstream raw materials:

[2,6-(iPr₂PO)₂C₆H₃]Ni(BH₄)

triethylamine

C₂₆H₄₇BNiO₂P₂

Downstream raw materials:

[2,6-((i)PrPO)2C₆H₃]NiOCH₂Ph