[Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)CHC(Me)N(2,4,6-trimethylphenyl))(μ-Cl)2Li(Me2NCH2CH2NMe2)]

Base Information

• Chemical Name: [Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)CHC(Me)N(2,4,6-trimethylphenyl))(μ-Cl)2Li(Me2NCH2CH2NMe2)]
• CAS No.: 887947-14-0
• Molecular Formula: C₄₇H₉₃Cl₂LiN₄Si₆Ti
• Molecular Weight: 1008.52
• Mol file: 887947-14-0.mol

Synonyms:[Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)CHC(Me)N(2,4,6-trimethylphenyl))(μ-Cl)2Li(Me2NCH2CH2NMe2)]

Chemical Property of [Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)CHC(Me)N(2,4,6-trimethylphenyl))(μ-Cl)2Li(Me2NCH2CH2NMe2)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)CHC(Me)N(2,4,6-trimethylphenyl))(μ-Cl)2Li(Me2NCH2CH2NMe2)]

There total 3 articles about [Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)CHC(Me)N(2,4,6-trimethylphenyl))(μ-Cl)2Li(Me2NCH2CH2NMe2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

tetrachlorobis(tetrahydrofuran)titanium(IV) (31011-57-1,112925-19-6,112925-18-5) + N,N,N,N,-tetramethylethylenediamine (110-18-9) + [Li(N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)C(Me)CHC(Me)N(2,4,6-trimethylphenyl))] (676321-94-1) → [Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)CHC(Me)N(2,4,6-trimethylphenyl))(μ-Cl)2Li(Me2NCH2CH2NMe2)] (887947-14-0)

Guidance literature:

With KC₈; In benzene; under Ar; KC8 added to benzene suspn. of Li compd. and Ti complex in presence of Me2NCH2CH2NMe2; stirred for 1 d; solvent removed under reduced pressure; toluene added; filtered through Celite; filtrate dried under vac.; recrystd. from hexane at 0°C; elem. anal.;

DOI:10.1021/om0509948

Reference yield:

titanium trichloride tris(tetrahydrofuran) (31168-87-3,18039-90-2) + N,N,N,N,-tetramethylethylenediamine (110-18-9) + [Li(N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)C(Me)CHC(Me)N(2,4,6-trimethylphenyl))] (676321-94-1) → [Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)CHC(Me)N(2,4,6-trimethylphenyl))(μ-Cl)2Li(Me2NCH2CH2NMe2)] (887947-14-0)

Guidance literature:

With K; In benzene; under Ar; K added to benzene suspn. of Li compd. and Ti complex in presence of Me2NCH2CH2NMe2; stirred for 1 d; solvent removed under reduced pressure; toluene added; filtered through Celite; filtrate dried under vac.; recrystd. from hexane at 0°C; detd. by (1)H NMR spectra;

DOI:10.1021/om0509948

Reference yield:

TiCl2(TMEDA)2 (131618-67-2) + [Li(N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)C(Me)CHC(Me)N(2,4,6-trimethylphenyl))] (676321-94-1) → [Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)CHC(Me)N(2,4,6-trimethylphenyl))(μ-Cl)2Li(Me2NCH2CH2NMe2)] (887947-14-0)

Guidance literature:

In benzene; under Ar; soln. of Li compd. in benzene added to slurry of Ti complex inbenzene; stirred for 1 d; solvent removed under reduced pressure; toluene added; filtered through Celite; filtrate dried under vac.; recrystd. from hexane at 0°C; detd. by (1)H NMR spectra;

DOI:10.1021/om0509948

upstream raw materials:

tetrachlorobis(tetrahydrofuran)titanium(IV)

N,N,N,N,-tetramethylethylenediamine

[Li(N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)C(Me)CHC(Me)N(2,4,6-trimethylphenyl))]

titanium trichloride tris(tetrahydrofuran)

Downstream raw materials:

[Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)(PMe₃)CH=C(Me)N(2,4,6-trimethylphenyl))Cl]

[Ti=N(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(C(Me)CH=C(Me)N(2,4,6-trimethylphenyl))Cl(pyridine)]