bis((N-salicylidene)-4,4'-diaminodiphenyl)thioether

Base Information

• Chemical Name: bis((N-salicylidene)-4,4'-diaminodiphenyl)thioether
• CAS No.: 3430-67-9
• Molecular Formula: C₂₆H₂₀N₂O₂S
• Molecular Weight: 424.523
• Mol file: 3430-67-9.mol

Synonyms:bis((N-salicylidene)-4,4'-diaminodiphenyl)thioether

Chemical Property of bis((N-salicylidene)-4,4'-diaminodiphenyl)thioether

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of bis((N-salicylidene)-4,4'-diaminodiphenyl)thioether

There total 2 articles about bis((N-salicylidene)-4,4'-diaminodiphenyl)thioether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

4,4'-thiobisaniline (139-65-1) + salicylaldehyde (90-02-8) → bis((N-salicylidene)-4,4'-diaminodiphenyl)thioether (3430-67-9)

Guidance literature:

In ethanol; at 78 ℃; for 3h;

DOI:10.1016/j.ica.2019.118979

Reference yield:

<2-Hydroxy-benzyliden>-4-rhodan-anilin (3378-58-3) → bis((N-salicylidene)-4,4'-diaminodiphenyl)thioether (3430-67-9)

Guidance literature:

nickel; In xylene; at 220 ℃; under 5 - 10 Torr;

DOI:10.1002/ardp.19652980705

Reference yield:

bis((N-salicylidene)-4,4'-diaminodiphenyl)thioether (3430-67-9) + thorium tetrachloride (10026-08-1) → Th(4+)*2Cl(1-)*C26H18N2O2S(2-) = Th(C26H18N2O2S)Cl2

Guidance literature:

In ethanol; byproducts: HCl; treating a soln. of ThCl4 in abs. ethanol with a slight excess of the ligand, evapn. to dryness at 70-80°C, the residue is heated at 180°C until the evoln. of HCl ceases; the cooled product was extracted with ethanol and dried;

upstream raw materials:

4,4'-thiobisaniline

salicylaldehyde

<2-Hydroxy-benzyliden>-4-rhodan-anilin