(2β,3β,3aα,5β)-3,3a,4,5-tetrahydro-5-methoxy-3-methyl-3a-<3-<(methylsulfonyl)oxy>propyl>-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone

Base Information

Chemical Name:(2β,3β,3aα,5β)-3,3a,4,5-tetrahydro-5-methoxy-3-methyl-3a-<3-<(methylsulfonyl)oxy>propyl>-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone
CAS No.:78108-40-4
Molecular Formula:C₂₃H₃₂O₉S
Molecular Weight:484.568
Hs Code.:

Synonyms:(2β,3β,3aα,5β)-3,3a,4,5-tetrahydro-5-methoxy-3-methyl-3a-<3-<(methylsulfonyl)oxy>propyl>-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone

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Chemical Property of (2β,3β,3aα,5β)-3,3a,4,5-tetrahydro-5-methoxy-3-methyl-3a-<3-<(methylsulfonyl)oxy>propyl>-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone

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Technology Process of (2β,3β,3aα,5β)-3,3a,4,5-tetrahydro-5-methoxy-3-methyl-3a-<3-<(methylsulfonyl)oxy>propyl>-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone

There total 1 articles about (2β,3β,3aα,5β)-3,3a,4,5-tetrahydro-5-methoxy-3-methyl-3a-<3-<(methylsulfonyl)oxy>propyl>-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 78111-20-3
(2β,3β,3aα)-3,3a-dihydro-5-methoxy-3-methyl-3a-<3-<(methylsulfonyl)oxy>propyl>-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone

: 78108-40-4
(2β,3β,3aα,5β)-3,3a,4,5-tetrahydro-5-methoxy-3-methyl-3a-<3-<(methylsulfonyl)oxy>propyl>-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone

Guidance literature:: With hydrogen; Rh on carbon; In methanol; for 1.75h;
DOI:10.1021/ja00400a039

Reference yield:

: 78108-40-4
(2β,3β,3aα,5β)-3,3a,4,5-tetrahydro-5-methoxy-3-methyl-3a-<3-<(methylsulfonyl)oxy>propyl>-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone

: 76202-43-2,78108-41-5,90898-97-8,112455-82-0,137491-87-3
(2β,3β,3aα,5β)-3,3a,4,5-tetrahydro-5-methoxy-3-methyl-3a-(2-propenyl)-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone

Guidance literature:: With sodium tetrahydroborate; sodium periodate; bis(p-chlorophenyl) diselenide; Yield given. Multistep reaction; 1.) ethanol, THF, 55 min, 2.) aq. THF, ethanol, 25 min, 70 deg C, 150 min;
DOI:10.1021/ja00400a039

Reference yield:

: 78108-40-4
(2β,3β,3aα,5β)-3,3a,4,5-tetrahydro-5-methoxy-3-methyl-3a-<3-<(methylsulfonyl)oxy>propyl>-2-(3,4,5-trimethoxyphenyl)-6(2H)-benzofuranone

: 64332-37-2,78148-79-5,96895-52-2,106973-35-7
d,l-megaphone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaBH₄, 4,4'-dichlorodiphenyl diselenide, 2.) sodium periodate / 1.) ethanol, THF, 55 min, 2.) aq. THF, ethanol, 25 min, 70 deg C, 150 min

2: 1.) DIBAH, 2.) trietnylamine, methanesulfonyl chloride / 1.) THF, hexane, 45 min, 2.) THF, -55 - -60 deg C, 15 min

With sodium tetrahydroborate; sodium periodate; bis(p-chlorophenyl) diselenide; diisobutylaluminium hydride; methanesulfonyl chloride; triethylamine;
DOI:10.1021/ja00400a039