1-(o-chlorophenyl)-3-(m-nitrophenyl)-5-phenylformazan

Base Information

• Chemical Name: 1-(o-chlorophenyl)-3-(m-nitrophenyl)-5-phenylformazan
• CAS No.: 1005341-73-0
• Molecular Formula: C₁₉H₁₄ClN₅O₂
• Molecular Weight: 379.805
• Mol file: 1005341-73-0.mol

Synonyms:1-(o-chlorophenyl)-3-(m-nitrophenyl)-5-phenylformazan

Chemical Property of 1-(o-chlorophenyl)-3-(m-nitrophenyl)-5-phenylformazan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of 1-(o-chlorophenyl)-3-(m-nitrophenyl)-5-phenylformazan

There total 1 articles about 1-(o-chlorophenyl)-3-(m-nitrophenyl)-5-phenylformazan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

o-chloroaniline (95-51-2) + 1-(3-nitrobenzylidene)-2-phenylhydrazine (7539-23-3) → 1-(o-chlorophenyl)-3-(m-nitrophenyl)-5-phenylformazan (1005341-73-0)

Guidance literature:

o-chloroaniline; With sodium nitrite; In neat (no solvent); at 20 ℃; Green chemistry;

1-(3-nitrobenzylidene)-2-phenylhydrazine; With sodium hydroxide; In neat (no solvent); at 20 ℃; pH=10 - 12; Green chemistry;

DOI:10.1246/bcsj.20140298

Reference yield: 79.0%

1-(o-chlorophenyl)-3-(m-nitrophenyl)-5-phenylformazan (1005341-73-0) + nickel(II) acetate tetrahydrate (6018-89-9) → bis[1-(o-chlorophenyl)-3-(m-nitrophenyl)-5-phenylformazanato]nickel(II) (1070904-29-8)

Guidance literature:

In 1,4-dioxane; ethanol; soln. of formazane deriv. in dioxane added to soln. of Ni salt in EtOH, mixt. stirred at 30-35°C under reflux for 8 h; soln. stored for 3 d, solid filtered off, washed with H2O and MeOH, recrystd. from MeOH, dried at 40°C for 24 h;

DOI:10.1016/j.saa.2007.10.010

upstream raw materials:

o-chloroaniline

1-(3-nitrobenzylidene)-2-phenylhydrazine

Downstream raw materials:

bis[1-(o-chlorophenyl)-3-(m-nitrophenyl)-5-phenylformazanato]nickel(II)