C₂₇H₄₄O₃Si

Base Information

Chemical Name:C₂₇H₄₄O₃Si
CAS No.:1345817-43-7
Molecular Formula:C₂₇H₄₄O₃Si
Molecular Weight:444.73
Hs Code.:

C<sub>27</sub>H<sub>44</sub>O<sub>3</sub>Si

Synonyms:C₂₇H₄₄O₃Si

Suppliers and Price of C₂₇H₄₄O₃Si

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₂₇H₄₄O₃Si

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₂₇H₄₄O₃Si

There total 12 articles about C₂₇H₄₄O₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 3587-60-8
Benzyloxymethyl chloride

: 1345817-42-6
(S,E)-1-((1S,5R)-5-((tert-butyldimethylsilyl)oxy)cyclopent-2-en-1-yl)oct-1-en-3-ol

: 1345817-43-7
C₂₇H₄₄O₃Si

Guidance literature:: With tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 30 ℃;
DOI:10.1021/ol202711k

Reference yield:

: 1345817-39-1
C₁₉H₃₄O₂Si

: 1345817-43-7
C₂₇H₄₄O₃Si

Guidance literature:: Multi-step reaction with 4 steps

1: pyridinium chlorochromate / dichloromethane / 20 °C

2: potassium hydroxide / dichloromethane; isopropyl alcohol / 16 h / 35 - 40 °C

3: sodium bis(2-methoxyethoxy)aluminium dihydride / tetrahydrofuran; toluene / 30 °C

4: tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine / dichloromethane / 30 °C

With tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; pyridinium chlorochromate; potassium hydroxide; In tetrahydrofuran; dichloromethane; isopropyl alcohol; toluene;
DOI:10.1021/ol202711k

Reference yield:

: 1345817-36-8
(1S,4R)-4-((tert-butyldimethylsilyl)oxy)cyclopent-2-en-1-yl picolinate

: 1345817-43-7
C₂₇H₄₄O₃Si

Guidance literature:: Multi-step reaction with 7 steps

1.1: copper acetylacetonate / tetrahydrofuran; dichloromethane / 0.5 h / 0 °C

1.2: 2 h / 0 °C

2.1: potassium carbonate / methanol / 20 °C

3.1: n-butyllithium / hexane / 0.67 h / -70 °C

3.2: 3 h / -70 °C

4.1: pyridinium chlorochromate / dichloromethane / 20 °C

5.1: potassium hydroxide / dichloromethane; isopropyl alcohol / 16 h / 35 - 40 °C

6.1: sodium bis(2-methoxyethoxy)aluminium dihydride / tetrahydrofuran; toluene / 30 °C

7.1: tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine / dichloromethane / 30 °C

With copper acetylacetonate; n-butyllithium; tetra-(n-butyl)ammonium iodide; potassium carbonate; N-ethyl-N,N-diisopropylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; pyridinium chlorochromate; potassium hydroxide; In tetrahydrofuran; methanol; hexane; dichloromethane; isopropyl alcohol; toluene;
DOI:10.1021/ol202711k