Benzoic acid (1R,2R,3R,4S)-4-hydroxy-2-((1E,5E)-(S)-3-hydroxy-octa-1,5-dienyl)-3-((E)-6-methoxycarbonyl-hex-2-enyl)-cyclopentyl ester

Base Information

Chemical Name:Benzoic acid (1R,2R,3R,4S)-4-hydroxy-2-((1E,5E)-(S)-3-hydroxy-octa-1,5-dienyl)-3-((E)-6-methoxycarbonyl-hex-2-enyl)-cyclopentyl ester
CAS No.:75351-59-6
Molecular Formula:C₂₈H₃₈O₆
Molecular Weight:470.606
Hs Code.:

Synonyms:Benzoic acid (1R,2R,3R,4S)-4-hydroxy-2-((1E,5E)-(S)-3-hydroxy-octa-1,5-dienyl)-3-((E)-6-methoxycarbonyl-hex-2-enyl)-cyclopentyl ester

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Chemical Property of Benzoic acid (1R,2R,3R,4S)-4-hydroxy-2-((1E,5E)-(S)-3-hydroxy-octa-1,5-dienyl)-3-((E)-6-methoxycarbonyl-hex-2-enyl)-cyclopentyl ester

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of Benzoic acid (1R,2R,3R,4S)-4-hydroxy-2-((1E,5E)-(S)-3-hydroxy-octa-1,5-dienyl)-3-((E)-6-methoxycarbonyl-hex-2-enyl)-cyclopentyl ester

There total 9 articles about Benzoic acid (1R,2R,3R,4S)-4-hydroxy-2-((1E,5E)-(S)-3-hydroxy-octa-1,5-dienyl)-3-((E)-6-methoxycarbonyl-hex-2-enyl)-cyclopentyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 75351-58-5
Benzoic acid (1R,2R,3R,4S)-3-((E)-6-methoxycarbonyl-hex-2-enyl)-4-(2,2,2-trichloro-acetoxy)-2-[(1E,5E)-(S)-3-(2,2,2-trichloro-acetoxy)-octa-1,5-dienyl]-cyclopentyl ester

: 75351-59-6
Benzoic acid (1R,2R,3R,4S)-4-hydroxy-2-((1E,5E)-(S)-3-hydroxy-octa-1,5-dienyl)-3-((E)-6-methoxycarbonyl-hex-2-enyl)-cyclopentyl ester

Guidance literature:: With potassium carbonate; In methanol; at 0 ℃; for 0.166667h;
DOI:10.1246/cl.1980.377

Reference yield:

: 75351-53-0
(3aR,4R,5R,6aS)-4-[(1E,5E)-(S)-3-(1-Methoxy-1-methyl-ethoxy)-octa-1,5-dienyl]-5-(tetrahydro-pyran-2-yloxy)-hexahydro-cyclopenta[b]furan-2-ol

: 75351-59-6
Benzoic acid (1R,2R,3R,4S)-4-hydroxy-2-((1E,5E)-(S)-3-hydroxy-octa-1,5-dienyl)-3-((E)-6-methoxycarbonyl-hex-2-enyl)-cyclopentyl ester

Guidance literature:: Multi-step reaction with 5 steps

2: pyridine / CH₂Cl₂ / 0.5 h / 0 °C

3: 57 percent / p-toluenesulphonic acid / methanol / Ambient temperature

4: pyridine / CH₂Cl₂

5: 93 percent / K₂CO₃ / methanol / 0.17 h / 0 °C

With pyridine; potassium carbonate; toluene-4-sulfonic acid; In methanol; dichloromethane;
DOI:10.1246/cl.1980.377

Reference yield:

: 75351-52-9
(3aR,4R,5R,6aS)-4-[(1E,5E)-(S)-3-(1-Methoxy-1-methyl-ethoxy)-octa-1,5-dienyl]-5-(tetrahydro-pyran-2-yloxy)-hexahydro-cyclopenta[b]furan-2-one

: 75351-59-6
Benzoic acid (1R,2R,3R,4S)-4-hydroxy-2-((1E,5E)-(S)-3-hydroxy-octa-1,5-dienyl)-3-((E)-6-methoxycarbonyl-hex-2-enyl)-cyclopentyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: diisobutylaluminium hydride / toluene / -78 °C

3: pyridine / CH₂Cl₂ / 0.5 h / 0 °C

4: 57 percent / p-toluenesulphonic acid / methanol / Ambient temperature

5: pyridine / CH₂Cl₂

6: 93 percent / K₂CO₃ / methanol / 0.17 h / 0 °C

With pyridine; diisobutylaluminium hydride; potassium carbonate; toluene-4-sulfonic acid; In methanol; dichloromethane; toluene;
DOI:10.1246/cl.1980.377