C₂₅H₃₀O₃Si

Base Information

• Chemical Name: C₂₅H₃₀O₃Si
• CAS No.: 1334173-57-7
• Molecular Formula: C₂₅H₃₀O₃Si
• Molecular Weight: 406.597
• Mol file: 1334173-57-7.mol

Synonyms:C₂₅H₃₀O₃Si

Chemical Property of C₂₅H₃₀O₃Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₅H₃₀O₃Si

There total 1 articles about C₂₅H₃₀O₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C26H34O4Si → C25H30O3Si + C25H30O3Si (1334173-57-7)

Guidance literature:

With pyridinium p-toluenesulfonate; In isopropyl alcohol; toluene; at 28 - 80 ℃; Inert atmosphere;

DOI:10.1002/anie.201103550

Reference yield: 70.0%

C25H30O3Si (1334173-57-7) + allyl bromide (106-95-6) → C28H34O3Si (1334173-58-8) + C28H34O3Si (1334173-59-9)

Guidance literature:

C₂₅H₃₀O₃Si; With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium hexamethyldisilazane; In tetrahydrofuran; at -78 - 0 ℃; Inert atmosphere;

allyl bromide; In tetrahydrofuran; at -78 ℃; for 13h; optical yield given as %de; Inert atmosphere;

DOI:10.1002/anie.201103550

Reference yield:

C25H30O3Si (1334173-57-7) → C28H44N2O11S (1334173-67-9)

Guidance literature:

Multi-step reaction with 13 steps

1.1: N,N,N,N,N,N-hexamethylphosphoric triamide; lithium hexamethyldisilazane / tetrahydrofuran / -78 - 0 °C / Inert atmosphere

1.2: 13 h / -78 °C / Inert atmosphere

2.1: lithium borohydride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

3.1: dicobalt octacarbonyl / toluene / 1.5 h / 20 °C / Inert atmosphere

3.2: 12 h / 100 °C

4.1: tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine / dichloromethane / 15 h / 20 °C / Inert atmosphere

5.1: borane-THF; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

6.1: sodium hydride / tetrahydrofuran; mineral oil / 0 - 20 °C / Inert atmosphere

6.2: 0 - 20 °C / Inert atmosphere

7.1: sodium hydrogencarbonate / 1,2-dichloro-benzene / 10 h / 170 °C / Inert atmosphere

8.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / 0 °C / Inert atmosphere

8.2: -78 - 20 °C / Inert atmosphere

9.1: dimethylsulfide borane complex / tetrahydrofuran; dimethylsulfide / 12.5 h / 0 °C / Inert atmosphere

9.2: 10 h / 0 °C / Inert atmosphere

9.3: NaBO₃*4H₂O / 4 h / 20 °C / Inert atmosphere

10.1: triethylamine / dichloromethane / 4 h / 0 °C / Inert atmosphere

11.1: dmap / pyridine; dichloromethane / 0 - 20 °C / Inert atmosphere

12.1: potassium carbonate / N,N-dimethyl-formamide / 4 h / 80 °C / Inert atmosphere

13.1: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

With N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; lithium borohydride; n-butyllithium; dicobalt octacarbonyl; borane-THF; dimethylsulfide borane complex; tetrabutyl ammonium fluoride; tetra-(n-butyl)ammonium iodide; sodium hydride; sodium hydrogencarbonate; potassium carbonate; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; lithium hexamethyldisilazane; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; pyridine; dimethylsulfide; hexane; dichloromethane; N,N-dimethyl-formamide; 1,2-dichloro-benzene; toluene; mineral oil; 3.1: Pauson-Khand reaction / 3.2: Pauson-Khand reaction;

DOI:10.1002/anie.201103550

Downstream raw materials:

C₂₈H₃₄O₃Si

C₂₉H₃₈O₄Si

C₃₃H₄₆O₆Si

C₃₃H₄₈O₆Si