Technology Process of C34H54O5Si
There total 9 articles about C34H54O5Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
diisobutylaluminium hydride;
In
hexane; dichloromethane;
at -78 ℃;
for 0.116667h;
Inert atmosphere;
DOI:10.1021/jo400260m
- Guidance literature:
-
Multi-step reaction with 8 steps
1: trifluorormethanesulfonic acid / dichloromethane; cyclohexane / 0.5 h / 20 °C / Inert atmosphere
2: diisobutylaluminium hydride / dichloromethane; hexane / 0.08 h / -78 °C / Inert atmosphere
3: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -20 °C / Inert atmosphere; Molecular sieve
4: dimethyl sulfoxide; sulfur trioxide pyridine complex; triethylamine / dichloromethane / 1.5 h / 0 °C / Inert atmosphere
5: dichloromethane / 0.02 h / 0 °C / Inert atmosphere
6: tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tributylphosphine; formic acid; triethylamine / 1,4-dioxane / 9.5 h / 20 °C / Inert atmosphere
7: 2,6-dimethylpyridine / dichloromethane / 0.33 h / 0 °C / Inert atmosphere
8: diisobutylaluminium hydride / dichloromethane; hexane / 0.12 h / -78 °C / Inert atmosphere
With
2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; formic acid; L-(+)-diisopropyl tartrate; tributylphosphine; trifluorormethanesulfonic acid; sulfur trioxide pyridine complex; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine;
In
1,4-dioxane; decane; hexane; dichloromethane; cyclohexane;
3: |Sharpless Asymmetric Epoxidation / 4: |Parikh-Doering Oxidation / 5: |Horner-Wadsworth-Emmons Olefination;
DOI:10.1021/jo400260m
- Guidance literature:
-
Multi-step reaction with 7 steps
1: diisobutylaluminium hydride / dichloromethane; hexane / 0.08 h / -78 °C / Inert atmosphere
2: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -20 °C / Inert atmosphere; Molecular sieve
3: dimethyl sulfoxide; sulfur trioxide pyridine complex; triethylamine / dichloromethane / 1.5 h / 0 °C / Inert atmosphere
4: dichloromethane / 0.02 h / 0 °C / Inert atmosphere
5: tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tributylphosphine; formic acid; triethylamine / 1,4-dioxane / 9.5 h / 20 °C / Inert atmosphere
6: 2,6-dimethylpyridine / dichloromethane / 0.33 h / 0 °C / Inert atmosphere
7: diisobutylaluminium hydride / dichloromethane; hexane / 0.12 h / -78 °C / Inert atmosphere
With
2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; formic acid; L-(+)-diisopropyl tartrate; tributylphosphine; sulfur trioxide pyridine complex; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine;
In
1,4-dioxane; decane; hexane; dichloromethane;
2: |Sharpless Asymmetric Epoxidation / 3: |Parikh-Doering Oxidation / 4: |Horner-Wadsworth-Emmons Olefination;
DOI:10.1021/jo400260m