4-methoxycarbonyl-2-nitrobenzyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

Base Information

Chemical Name:4-methoxycarbonyl-2-nitrobenzyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside
CAS No.:89950-94-7
Molecular Formula:C₂₃H₂₇NO₁₄
Molecular Weight:541.466
Hs Code.:

Synonyms:4-methoxycarbonyl-2-nitrobenzyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

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Chemical Property of 4-methoxycarbonyl-2-nitrobenzyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

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Technology Process of 4-methoxycarbonyl-2-nitrobenzyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

There total 3 articles about 4-methoxycarbonyl-2-nitrobenzyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 89950-93-6
methyl 4-(hydroxymethyl)-3-nitrobenzoate

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 89950-94-7
4-methoxycarbonyl-2-nitrobenzyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

Guidance literature:: With calcium sulfate; nitromethane; silver perchlorate; calcium carbonate;
DOI:10.1016/0008-6215(83)88352-9

Reference yield:

: 55715-03-2
4-bromomethyl-3-nitrobenzoic acid

: 89950-94-7
4-methoxycarbonyl-2-nitrobenzyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) sodium acetate; 2.) 1M hydrogen chloride / 1.) acetic acid, reflux, 24 h; 2.) acetic acid, reflux

2: 48 percent / calcium sulfate, calcium carbonate, nitromethane, silver perchlorate

With hydrogenchloride; calcium sulfate; nitromethane; sodium acetate; silver perchlorate; calcium carbonate;
DOI:10.1016/0008-6215(83)88352-9

Reference yield:

: 89950-93-6
methyl 4-(hydroxymethyl)-3-nitrobenzoate

: 439-03-2,439-04-3,439-05-4,2823-44-1,2823-46-3,3934-29-0,4163-44-4,4163-45-5,20409-31-8,23235-96-3,51897-75-7,51897-76-8,51897-77-9,57573-38-3,62561-28-8,126641-47-2
2,3,4,6-tetra-O-acetyl-1-fluoro-α-D-glucopyranose

: 89950-94-7
4-methoxycarbonyl-2-nitrobenzyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

Guidance literature:: With molecular sieve; boron trifluoride diethyl etherate; Yield given. Multistep reaction; 1.) dichloromethane, 1 h, 2.) 2 h;
DOI:10.1016/0008-6215(89)85131-6