tert-Butyl-[(2R,6S)-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octyloxy]-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-[(2R,6S)-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octyloxy]-diphenyl-silane
CAS No.:186642-00-2
Molecular Formula:C₃₅H₅₄OSi
Molecular Weight:518.899
Hs Code.:

Synonyms:tert-Butyl-[(2R,6S)-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octyloxy]-diphenyl-silane

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Chemical Property of tert-Butyl-[(2R,6S)-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octyloxy]-diphenyl-silane

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Technology Process of tert-Butyl-[(2R,6S)-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octyloxy]-diphenyl-silane

There total 6 articles about tert-Butyl-[(2R,6S)-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octyloxy]-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 186641-97-4
[(2R,6S)-8-Benzenesulfonyl-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octyloxy]-tert-butyl-diphenyl-silane

: 186642-00-2
tert-Butyl-[(2R,6S)-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octyloxy]-diphenyl-silane

Guidance literature:: With disodium hydrogenphosphate; sodium amalgam; In methanol; for 12h; Ambient temperature;
DOI:10.1016/0040-4020(96)00916-7

Reference yield:

: (E)-(2S,6R)-7-(tert-Butyl-diphenyl-silanyloxy)-2,6-dimethyl-hept-3-en-1-ol

: 186642-00-2
tert-Butyl-[(2R,6S)-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octyloxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 5 steps

1: 80 percent / H₂, sodium nitrite / 10percent Pd/C / methanol / 12 h

2: 98 percent / pyridine / 0.33 h / Ambient temperature

3: 94 percent / tetrabutylammonium bromide / dimethylformamide / 5 h / 60 °C

4: 1.) n-butyllithium / 1.) THF, HMPA, hexane, a) -78 deg C to, 10 min, b) RT, 1 h, 2.) THF, HMPA, hexane, -78 deg C, 4 h

5: 94 percent / Na-Hg, Na₂HPO₄ / methanol / 12 h / Ambient temperature

With pyridine; disodium hydrogenphosphate; n-butyllithium; sodium amalgam; tetrabutylammomium bromide; hydrogen; sodium nitrite; palladium on activated charcoal; In methanol; N,N-dimethyl-formamide;
DOI:10.1016/0040-4020(96)00916-7

Reference yield:

: 56691-74-8
{[(2,6,6-trimethyl-1-cyclohexen-1-yl)methyl]sulfonyl}benzene

: 186642-00-2
tert-Butyl-[(2R,6S)-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octyloxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) n-butyllithium / 1.) THF, HMPA, hexane, a) -78 deg C to, 10 min, b) RT, 1 h, 2.) THF, HMPA, hexane, -78 deg C, 4 h

2: 94 percent / Na-Hg, Na₂HPO₄ / methanol / 12 h / Ambient temperature

With disodium hydrogenphosphate; n-butyllithium; sodium amalgam; In methanol;
DOI:10.1016/0040-4020(96)00916-7