N(F(C₆H₃)P(i-Pr)2)2PdCl

Base Information

• Chemical Name: N(F(C₆H₃)P(i-Pr)2)2PdCl
• CAS No.: 779333-75-4
• Molecular Formula: C₂₄H₃₄ClF₂NP₂Pd
• Molecular Weight: 578.358
• Mol file: 779333-75-4.mol

Synonyms:N(F(C₆H₃)P(i-Pr)2)2PdCl

Chemical Property of N(F(C₆H₃)P(i-Pr)2)2PdCl

Chemical Property:

Purity/Quality:

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Technology Process of N(F(C₆H₃)P(i-Pr)2)2PdCl

There total 1 articles about N(F(C₆H₃)P(i-Pr)2)2PdCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Zn(Pd(N(FC6H3P(C3H7)2)2))2] (1000391-90-1) + ClSiPh3 (56994-72-0) → N(F(C6H3)P(i-Pr)2)2PdCl (779333-75-4) + zinc(II) chloride (7646-85-7,24359-56-6)

Guidance literature:

In not given; >4 equiv. Ph3PCl;

DOI:10.1039/b709364k

Reference yield: 35.0%

N(F(C6H3)P(i-Pr)2)2PdCl (779333-75-4) + phenyllithium (591-51-5) → N(F(C6H3)P(i-Pr)2)2PdPh (923566-51-2)

Guidance literature:

In diethyl ether; toluene; under Ar, Schlenk technique or glovebox; 2.0 M soln. of PhLi (1.29 mmol)in Et2O added to soln. of Pd complex (0.865 mmol) in toluene; mixt. sti rred for 1 h; filtered through silica; filtrate evapd. under vac.; residue dissolved in ether; cooled at -35°C;

DOI:10.1016/j.ica.2006.07.067

upstream raw materials:

[Zn(Pd(N(FC₆H₃P(C₃H₇)2)2))2]

ClSiPh₃

Downstream raw materials:

N(F(C₆H₃)P(i-Pr)2)2PdPh