prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate

Base Information

Chemical Name:prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate
CAS No.:1314757-17-9
Molecular Formula:C₈₈H₁₆₈O₁₃Si₆
Molecular Weight:1602.81
Hs Code.:

prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate

Synonyms:prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate

Suppliers and Price of prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate

There total 2 articles about prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1314757-15-7
C₄₆H₇₈O₉Si₂

: 1314757-14-6
2-[(3RS,7S,9R,10R)-7,10-bis-tert-butyldimethylsilyloxy-2,2-dimethyl-3-triethylsilyloxy-5-[(E)-2-triisopropylsilyloxyethylidene]-9-trimethylsilyloxyundecan-1-ylsulfonyl]benzothiazole

: 1314757-17-9
prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate

Guidance literature:: 2-[(3RS,7S,9R,10R)-7,10-bis-tert-butyldimethylsilyloxy-2,2-dimethyl-3-triethylsilyloxy-5-[(E)-2-triisopropylsilyloxyethylidene]-9-trimethylsilyloxyundecan-1-ylsulfonyl]benzothiazole; With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 - -60 ℃; for 0.5h;

C₄₆H₇₈O₉Si₂; In tetrahydrofuran; at -78 - 20 ℃; for 1.33333h;

With pyridinium p-toluenesulfonate; trimethyl orthoformate; In methanol; dichloromethane; at 20 ℃; for 1h;
DOI:10.1039/c7ob02129a

Reference yield:

: 1314757-16-8
C₉₁H₁₇₆O₁₃Si₇

: 1314757-17-9
prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate

Guidance literature:: With pyridinium p-toluenesulfonate; trimethyl orthoformate; In methanol; dichloromethane; at 20 ℃; for 1h; optical yield given as %de;
DOI:10.1039/c1cc12332g

Reference yield:

: 1314757-17-9
prop-2-enyl (3R,5S,7S,9S,11S,15R,19RS,23S,25R,26R,16E)-7-benzyloxy-3,23,26-tris-tert-butyldimethylsilyloxy-5,9-epoxy-11,15-epoxy-19-triethylsilyloxy-25-hydroxy-21-[(E)-2-triisopropylsilyloxyethylidene]-13-[(Z)-2-triisopropylsilyloxyethylidene]-9-methoxy-8,8,18,18-tetramethylheptacos-16-enoate

: 1314757-19-1
C₈₅H₁₆₄O₁₃Si₆

Guidance literature:: With morpholine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 16h;
DOI:10.1039/c1cc12332g