prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-β-D-glucopyranosyl}-α-D-glucopyranoside

Base Information

Chemical Name:prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-β-D-glucopyranosyl}-α-D-glucopyranoside
CAS No.:1419711-20-8
Molecular Formula:C₄₄H₅₅NO₁₃Si
Molecular Weight:834.005
Hs Code.:

prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-β-D-glucopyranosyl}-α-D-glucopyranoside

Synonyms:prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-β-D-glucopyranosyl}-α-D-glucopyranoside

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Chemical Property of prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-β-D-glucopyranosyl}-α-D-glucopyranoside

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Technology Process of prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-β-D-glucopyranosyl}-α-D-glucopyranoside

There total 3 articles about prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-β-D-glucopyranosyl}-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 1419711-15-1
prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-6-O-(4-methoxybenzyl)-β-D-glucopyranosyl}-α-D-glucopyranoside

: 1419711-20-8
prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-β-D-glucopyranosyl}-α-D-glucopyranoside

Guidance literature:: With sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; at 20 ℃; for 5h; Inert atmosphere;
DOI:10.1016/j.bmc.2012.11.025

Reference yield:

: 74984-84-2
prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside

: 1419711-20-8
prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-β-D-glucopyranosyl}-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: N-iodo-succinimide; silver trifluoromethanesulfonate / dichloromethane / 1 h / 0 - 20 °C / Molecular sieve; Inert atmosphere

2: sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone / water; dichloromethane / 5 h / 20 °C / Inert atmosphere

With N-iodo-succinimide; silver trifluoromethanesulfonate; sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water;
DOI:10.1016/j.bmc.2012.11.025

Reference yield:

: C₄₁H₄₈O₈SSi

: 1419711-20-8
prop-2-en-1-yl 2-(acetylamino)-4,6-O-benzylidene-2-deoxy-3-O-{2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-β-D-glucopyranosyl}-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: N-iodo-succinimide; silver trifluoromethanesulfonate / dichloromethane / 1 h / 0 - 20 °C / Molecular sieve; Inert atmosphere

2: sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone / water; dichloromethane / 5 h / 20 °C / Inert atmosphere

With N-iodo-succinimide; silver trifluoromethanesulfonate; sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water;
DOI:10.1016/j.bmc.2012.11.025