Technology Process of C29H18N2O
There total 7 articles about C29H18N2O which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl-t-butyl ether; potassium carbonate; cesium pivalate;
In
toluene;
at 100 ℃;
for 18h;
Inert atmosphere;
DOI:10.1016/j.tet.2013.01.001
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: bis(dibenzylideneacetone)-palladium(0); triphenylphosphine; cesium fluoride / 1,2-dimethoxyethane / 16 h / 90 °C / Inert atmosphere
2.1: caesium carbonate / methanol / 14 h / 70 °C / Inert atmosphere
3.1: potassium hydroxide; tetra(n-butyl)ammonium hydrogensulfate / dichloromethane / 0.33 h / 50 °C / Inert atmosphere
4.1: dichloromethane / 0 °C / Inert atmosphere
4.2: 0.5 h / 0 °C / Inert atmosphere
5.1: chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl-t-butyl ether; potassium carbonate; cesium pivalate / toluene / 18 h / 100 °C / Inert atmosphere
With
chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl-t-butyl ether; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; caesium carbonate; triphenylphosphine; cesium pivalate; cesium fluoride; potassium hydroxide; bis(dibenzylideneacetone)-palladium(0);
In
methanol; 1,2-dimethoxyethane; dichloromethane; toluene;
1.1: |Suzuki-Miyaura Coupling;
DOI:10.1016/j.tet.2013.01.001
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: potassium hydroxide; tetra(n-butyl)ammonium hydrogensulfate / dichloromethane / 0.5 h / 20 °C / Inert atmosphere
2.1: bis(dibenzylideneacetone)-palladium(0); triphenylphosphine; cesium fluoride / 1,2-dimethoxyethane / 16 h / 90 °C / Inert atmosphere
3.1: caesium carbonate / methanol / 14 h / 70 °C / Inert atmosphere
4.1: potassium hydroxide; tetra(n-butyl)ammonium hydrogensulfate / dichloromethane / 0.33 h / 50 °C / Inert atmosphere
5.1: dichloromethane / 0 °C / Inert atmosphere
5.2: 0.5 h / 0 °C / Inert atmosphere
6.1: chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl-t-butyl ether; potassium carbonate; cesium pivalate / toluene / 18 h / 100 °C / Inert atmosphere
With
chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl-t-butyl ether; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; caesium carbonate; triphenylphosphine; cesium pivalate; cesium fluoride; potassium hydroxide; bis(dibenzylideneacetone)-palladium(0);
In
methanol; 1,2-dimethoxyethane; dichloromethane; toluene;
2.1: |Suzuki-Miyaura Coupling;
DOI:10.1016/j.tet.2013.01.001