methyl 2-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-4,6-O-benzylidene-β-D-mannopyranoside

Base Information

Chemical Name:methyl 2-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-4,6-O-benzylidene-β-D-mannopyranoside
CAS No.:801291-57-6
Molecular Formula:C₂₈H₃₅FO₁₄
Molecular Weight:614.576
Hs Code.:

Synonyms:methyl 2-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-4,6-O-benzylidene-β-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 2-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-4,6-O-benzylidene-β-D-mannopyranoside

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Technology Process of methyl 2-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-4,6-O-benzylidene-β-D-mannopyranoside

There total 1 articles about methyl 2-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-4,6-O-benzylidene-β-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 108-24-7
acetic anhydride

: 144607-27-2
Methyl 2-O-acetyl-4,6-O-(phenylmethylene)-β-D-mannopyranoside

: 801291-55-4
3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl bromide

: methyl 2,3-di-O-acetyl-4,6-O-benzylidene-β-D-mannopyranoside

: 801291-57-6
methyl 2-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-4,6-O-benzylidene-β-D-mannopyranoside

Guidance literature:: Methyl 2-O-acetyl-4,6-O-(phenylmethylene)-β-D-mannopyranoside; 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl bromide; With 4 A molecular sieve; mercury(II) cyanide; mercury dibromide; In acetonitrile; at 20 ℃; for 12h;

acetic anhydride; In pyridine; at 20 ℃;
DOI:10.1016/j.carres.2004.08.007

Reference yield: 52.0%

: 801291-57-6
methyl 2-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-4,6-O-benzylidene-β-D-mannopyranoside

: 801291-59-8
methyl 2-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-6-O-benzyl-β-D-mannopyranoside

Guidance literature:: With aluminium trichloride; 4 A molecular sieve; trimethylamine borane; In diethyl ether; dichloromethane; at 0 ℃; for 1h;
DOI:10.1016/j.carres.2004.08.007

Reference yield:

: 801291-57-6
methyl 2-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-4,6-O-benzylidene-β-D-mannopyranoside

: 801291-61-2
methyl 2,4-di-O-acetyl-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl)-(1->3)-6-O-benzyl-β-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 52 percent / 4 Angstroem molecular sieves; trimethylamine borane; aluminum trichloride / CH₂Cl₂; diethyl ether / 1 h / 0 °C

2: 90 percent / pyridine / 20 °C

With aluminium trichloride; 4 A molecular sieve; trimethylamine borane; In pyridine; diethyl ether; dichloromethane;
DOI:10.1016/j.carres.2004.08.007