4-methylphenyl dithiocarbamic acid triethylammonium

Base Information

• Chemical Name: 4-methylphenyl dithiocarbamic acid triethylammonium
• CAS No.: 43009-17-2
• Molecular Formula: C₆H₁₅N*C₈H₉NS₂
• Molecular Weight: 284.49
• Mol file: 43009-17-2.mol

Synonyms:4-methylphenyl dithiocarbamic acid triethylammonium

Chemical Property of 4-methylphenyl dithiocarbamic acid triethylammonium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-methylphenyl dithiocarbamic acid triethylammonium

There total 2 articles about 4-methylphenyl dithiocarbamic acid triethylammonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

carbon disulfide (75-15-0,12122-00-8) + p-toluidine (106-49-0,12221-03-3) + triethylamine (121-44-8) → 4-methylphenyl dithiocarbamic acid triethylammonium (43009-17-2)

Guidance literature:

In diethyl ether; at 20 ℃; for 10h;

Reference yield: 59.1%

→ 4-methylphenyl dithiocarbamic acid triethylammonium (43009-17-2)

Guidance literature:

In diethyl ether; at 20 ℃; for 10h;

Reference yield: 92.0%

4-methylphenyl dithiocarbamic acid triethylammonium (43009-17-2) → 1-isothiocyanato-4-methylbenzene (622-59-3)

Guidance literature:

With [bis(acetoxy)iodo]benzene; triethylamine; In acetonitrile; Cooling with ice;

DOI:10.1002/ejoc.200800901

upstream raw materials:

carbon disulfide

p-toluidine

triethylamine

Downstream raw materials:

5-phenylimino-4-p-tolyl-3-thio-1,2,4-thiadiazolidine

5-thio-2-phenylimino-4-p-tolyl-1,3,4-dithiazolidine

C₁₁H₁₃NO₂S₂

1-isothiocyanato-4-methylbenzene

Refernces

• 1、 Tang,Niu,Wang,Huo,Li,Luo,Cao. "p-Aromatic Isothiocyanates: Synthesis and Anti Plant Pathogen Activity". . p. 1252 - 1257. Retrieved 2018/08/16.
• 2、 Mandapati, UshaRani,Pinapati, Srinivasarao,Rudraraju, RameshRaju. "Copper promoted desulfurization towards the synthesis of isothiocyanates". supporting information. p. 125 - 128. Retrieved 2016/12/26.