C₃₇H₅₆O₅Si

Base Information

Chemical Name:C₃₇H₅₆O₅Si
CAS No.:198336-11-7
Molecular Formula:C₃₇H₅₆O₅Si
Molecular Weight:608.934
Hs Code.:

C<sub>37</sub>H<sub>56</sub>O<sub>5</sub>Si

Synonyms:C₃₇H₅₆O₅Si

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Chemical Property of C₃₇H₅₆O₅Si

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Technology Process of C₃₇H₅₆O₅Si

There total 27 articles about C₃₇H₅₆O₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 213675-31-1
C₄₀H₆₄O₅Si₂

: 198336-11-7
C₃₇H₅₆O₅Si

Guidance literature:: With pyridinium p-toluenesulfonate; In methanol; at 25 ℃; for 0.5h;
DOI:10.1021/ja973000g DOI:10.1021/ja981062g

Reference yield:

: 2244-16-8,6485-40-1
(S)-p-mentha-6,8-dien-2-one

: 198336-11-7
C₃₇H₅₆O₅Si

Guidance literature:: Multi-step reaction with 26 steps

1: H₂O₂, NaOH / methanol / 2 h / 0 °C

2: H₂ / PtO₂ / ethanol / 12 h / 25 °C

3: 1.) LDA / 2.) THF, from -78 to 0 deg C, 2 h

4: Et₃N / CH₂Cl₂ / 12 h

5: 93 percent / L-selectride / tetrahydrofuran / 2 h / -78 °C

6: Et₃N / CH₂Cl₂ / 0.5 h / 0 °C

7: sodium naphthalenide / tetrahydrofuran / 0.5 h / 0 °C

8: 74 percent / propionic acid / 72 h / 170 °C

9: 97 percent / DIBAL / CH₂Cl₂ / 0.5 h / -78 °C

10: 1.) NaH / 1.) THF, 25 deg C, 30 min, 2.) THF, from 0 to 25 deg C, 5 h

11: 91 percent / DIBAL / CH₂Cl₂ / 2 h / -78 °C

12: 91 percent / diethyl L-tartrate, mol. sieves 4A, Ti(OiPr)4, t-BuOOH / CH₂Cl₂ / 8 h / -20 °C

13: Et₃N / CH₂Cl₂ / 1 h / -20 °C

14: sodium naphthalenide / tetrahydrofuran / 0.17 h / 0 °C

15: pyridinium p-toluenesulfonate / CH₂Cl₂ / 48 h / 25 °C

16: 1.) Hg(OAc)2, 2.) Li₂PdCl₄, CuCl₂ / 1.) MeOH, 25 deg C, 12 h, 2.) MeOH, 55 deg C, 3 h

17: CH₂Cl₂; tetrahydrofuran / 6 h / -78 °C

18: TBAF / tetrahydrofuran / 2 h / 25 °C

19: Dess-Martin periodinane, NaHCO₃, pyridine / 4 h / 25 °C

20: β-alanine / aq. ethanol / 72 h / 25 °C

21: (iPr)2NEt / CH₂Cl₂ / 2 h / -78 °C

22: 80 percent / DIBAL / hexane; tetrahydrofuran / 5 h / -78 - -40 °C

23: 91 percent / iPr₂NEt / CH₂Cl₂ / 1 h / -78 °C

24: LiHMDS / tetrahydrofuran / 0.17 h / 25 °C

25: NaHCO₃, Dess-Martin periodinane / CH₂Cl₂ / 4 h / 25 °C

26: 94 percent / PPTS / methanol / 0.5 h / 25 °C

With pyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium hydroxide; lithium tetrachloropalladate(II); diethyl (2R,3R)-tartrate; 4 A molecular sieve; mercury(II) diacetate; tetrabutyl ammonium fluoride; hydrogen; dihydrogen peroxide; pyridinium p-toluenesulfonate; L-Selectride; sodium naphthalenide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; propionic acid; triethylamine; N-ethyl-N,N-diisopropylamine; copper dichloride; lithium hexamethyldisilazane; lithium diisopropyl amide; 3-amino propanoic acid; platinum(IV) oxide; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane;
DOI:10.1021/ja981062g

Reference yield:

: 39903-97-4
(S)-carvone oxide

: 198336-11-7
C₃₇H₅₆O₅Si

Guidance literature:: Multi-step reaction with 25 steps

1: H₂ / PtO₂ / ethanol / 12 h / 25 °C

2: 1.) LDA / 2.) THF, from -78 to 0 deg C, 2 h

3: Et₃N / CH₂Cl₂ / 12 h

4: 93 percent / L-selectride / tetrahydrofuran / 2 h / -78 °C

5: Et₃N / CH₂Cl₂ / 0.5 h / 0 °C

6: sodium naphthalenide / tetrahydrofuran / 0.5 h / 0 °C

7: 74 percent / propionic acid / 72 h / 170 °C

8: 97 percent / DIBAL / CH₂Cl₂ / 0.5 h / -78 °C

9: 1.) NaH / 1.) THF, 25 deg C, 30 min, 2.) THF, from 0 to 25 deg C, 5 h

10: 91 percent / DIBAL / CH₂Cl₂ / 2 h / -78 °C

11: 91 percent / diethyl L-tartrate, mol. sieves 4A, Ti(OiPr)4, t-BuOOH / CH₂Cl₂ / 8 h / -20 °C

12: Et₃N / CH₂Cl₂ / 1 h / -20 °C

13: sodium naphthalenide / tetrahydrofuran / 0.17 h / 0 °C

14: pyridinium p-toluenesulfonate / CH₂Cl₂ / 48 h / 25 °C

15: 1.) Hg(OAc)2, 2.) Li₂PdCl₄, CuCl₂ / 1.) MeOH, 25 deg C, 12 h, 2.) MeOH, 55 deg C, 3 h

16: CH₂Cl₂; tetrahydrofuran / 6 h / -78 °C

17: TBAF / tetrahydrofuran / 2 h / 25 °C

18: Dess-Martin periodinane, NaHCO₃, pyridine / 4 h / 25 °C

19: β-alanine / aq. ethanol / 72 h / 25 °C

20: (iPr)2NEt / CH₂Cl₂ / 2 h / -78 °C

21: 80 percent / DIBAL / hexane; tetrahydrofuran / 5 h / -78 - -40 °C

22: 91 percent / iPr₂NEt / CH₂Cl₂ / 1 h / -78 °C

23: LiHMDS / tetrahydrofuran / 0.17 h / 25 °C

24: NaHCO₃, Dess-Martin periodinane / CH₂Cl₂ / 4 h / 25 °C

25: 94 percent / PPTS / methanol / 0.5 h / 25 °C

With pyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; lithium tetrachloropalladate(II); diethyl (2R,3R)-tartrate; 4 A molecular sieve; mercury(II) diacetate; tetrabutyl ammonium fluoride; hydrogen; pyridinium p-toluenesulfonate; L-Selectride; sodium naphthalenide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; propionic acid; triethylamine; N-ethyl-N,N-diisopropylamine; copper dichloride; lithium hexamethyldisilazane; lithium diisopropyl amide; 3-amino propanoic acid; platinum(IV) oxide; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane;
DOI:10.1021/ja981062g