(1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) D-α-bromocamphor-π-sulfonate

Base Information

Chemical Name:(1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) D-α-bromocamphor-π-sulfonate
CAS No.:81203-17-0
Molecular Formula:C₁₀H₁₄BrO₄S*C₄₂H₄₀P₂Rh
Molecular Weight:1019.82
Hs Code.:

Synonyms:(1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) D-α-bromocamphor-π-sulfonate

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Chemical Property of (1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) D-α-bromocamphor-π-sulfonate

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Technology Process of (1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) D-α-bromocamphor-π-sulfonate

There total 1 articles about (1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) D-α-bromocamphor-π-sulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: acethylacetonato(1,5-cyclooctadiene)rhodium(I)

: silver bromcamphorsulfonate

: 81157-85-9
bis(α-napthylphenylphosphino)ethane

: 81203-17-0
(1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) D-α-bromocamphor-π-sulfonate

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; to ice cold soln. of complex conc. HCl was added and stirred for 10 min, cold soln. of ligand was added dropwise and stirred for 2 h in an ice bath, after addition of sulfonate stirring was continued for 3 h in a cold, dark environment; evapn. in vac., recrystn. (addin ether to THF soln.); elem. anal.;
DOI:10.1021/ic00136a002

Reference yield:

: 81203-17-0
(1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) D-α-bromocamphor-π-sulfonate

: sodium perchlorate

: 81244-59-9
(+)-(1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) perchlorate

: 81244-58-8
(-)-(1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) perchlorate

Guidance literature:: In tetrahydrofuran; racemate was resolved by stirring its ether soln. at room temp. for 10 h followed by fractional pptn.; pure isomers in cold THF were treated separately with satd. NaClO4; pptn. from THF with ether; elem. anal.;
DOI:10.1021/ic00136a002

Reference yield:

: 7647-01-0,15364-23-5
hydrogenchloride

: 81203-17-0
(1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) D-α-bromocamphor-π-sulfonate

: 81244-57-7
(+)-(1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) chloride

: 81244-56-6
(-)-(1,5-cyclooctadiene)(bis(α-napthylphenylphosphino)ethane)rhodium(I) chloride

Guidance literature:: In tetrahydrofuran; racemate was resolved by stirring its ether soln. at room temp. for 10 h followed by fractional pptn.; pure isomers were treated separately with HCl in cold THF; pptn. from THF with ether; elem. anal.;
DOI:10.1021/ic00136a002