[7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid

Base Information

Chemical Name:[7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid
CAS No.:845512-95-0
Molecular Formula:C₄₉H₈₂O₈Si₃
Molecular Weight:883.442
Hs Code.:

[7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid

Synonyms:[7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid

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Chemical Property of [7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid

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Technology Process of [7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid

There total 7 articles about [7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 884005-51-0
C₄₉H₈₂O₇Si₃

: 845512-95-0
[7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid

Guidance literature:: With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; In tert-butyl alcohol; at 20 ℃; for 0.5h;
DOI:10.1002/chem.200500994

Reference yield:

: 884004-92-6
7-(3-benzyloxy-propyl)-4a,10a-dimethyl-5-(triisopropyl-silanyloxy)-2-[2-(triisopropyl-silanyloxy)-ethyl]-decahydro-1,8,10-trioxa-anthracen-3-ol

: 845512-95-0
[7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid

Guidance literature:: Multi-step reaction with 7 steps

1: 89 percent / lithium 4,4'-di-tert-butylbiphenyl / tetrahydrofuran / 0.5 h / -78 - -40 °C

2: 95 percent / NEt₃; DMAP / CH₂Cl₂ / 0.5 h / -78 °C

3: 92 percent / 10-camphorsulfonic acid / CH₂Cl₂ / 2.5 h / 20 °C

4: 100 percent / NEt₃; DMAP / CH₂Cl₂ / 0.7 h / 20 °C

5: 97 percent / aq. AcOH / tetrahydrofuran / 8 h / 0 °C

6: NMO; 4 Angstroem molecular sieves / tetrapropylammonium perruthenate / CH₂Cl₂ / 0.6 h / 20 °C

7: 0.286 g / aq. NaClO₂; 2-methyl-2-butene; NaH₂PO₄ / 2-methyl-propan-2-ol / 0.5 h / 20 °C

With dmap; sodium chlorite; sodium dihydrogenphosphate; N-methyl-2-indolinone; 2-methyl-but-2-ene; 4 A molecular sieve; (1S)-10-camphorsulfonic acid; lithium 4,4′-di-tert-butylbiphenylide; acetic acid; triethylamine; tetrapropylammonium perruthennate; In tetrahydrofuran; dichloromethane; tert-butyl alcohol;
DOI:10.1002/chem.200500994

Reference yield:

: 884005-48-5
7-(3-hydroxy-propyl)-4a,10a-dimethyl-5-(triisopropyl-silanyloxy)-2-[2-(triisopropyl-silanyloxy)-ethyl]-decahydro-1,8,10-trioxa-anthracen-3-ol

: 845512-95-0
[7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid

Guidance literature:: Multi-step reaction with 6 steps

1: 95 percent / NEt₃; DMAP / CH₂Cl₂ / 0.5 h / -78 °C

2: 92 percent / 10-camphorsulfonic acid / CH₂Cl₂ / 2.5 h / 20 °C

3: 100 percent / NEt₃; DMAP / CH₂Cl₂ / 0.7 h / 20 °C

4: 97 percent / aq. AcOH / tetrahydrofuran / 8 h / 0 °C

5: NMO; 4 Angstroem molecular sieves / tetrapropylammonium perruthenate / CH₂Cl₂ / 0.6 h / 20 °C

6: 0.286 g / aq. NaClO₂; 2-methyl-2-butene; NaH₂PO₄ / 2-methyl-propan-2-ol / 0.5 h / 20 °C

With dmap; sodium chlorite; sodium dihydrogenphosphate; N-methyl-2-indolinone; 2-methyl-but-2-ene; 4 A molecular sieve; (1S)-10-camphorsulfonic acid; acetic acid; triethylamine; tetrapropylammonium perruthennate; In tetrahydrofuran; dichloromethane; tert-butyl alcohol;
DOI:10.1002/chem.200500994