(R)-2-Diphenyphosphino-2'-hydroxyl-1,1'-binaphthyl

Base Information

Chemical Name:(R)-2-Diphenyphosphino-2'-hydroxyl-1,1'-binaphthyl
CAS No.:149917-88-4
Molecular Formula:C₃₂H₂₃OP
Molecular Weight:454.508
Hs Code.:29209090
Mol file:149917-88-4.mol

Synonyms:[1,1'-Binaphthalen]-2-ol,2'-(diphenylphosphino)-, (R)-; (1R)-2'-(Diphenylphosphino)-1,1'-binaphthalenyl-2-ol;(1R)-2'-(Diphenylphosphino)[1,1'-binaphthalen]-2-ol

Suppliers and Price of (R)-2-Diphenyphosphino-2'-hydroxyl-1,1'-binaphthyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(R)-(+)-DIPHENYLPHOSPHINO-2'-HYDROXY-1,1'-BINAPHTHYL 95.00%
50MG
$ 238.35

American Custom Chemicals Corporation
(R)-(+)-DIPHENYLPHOSPHINO-2'-HYDROXY-1,1'-BINAPHTHYL 95.00%
250MG
$ 914.41

Alfa Aesar
(R)-(+)-2'-Diphenylphosphino-1,1'-binaphth-2-ol, 96%
250mg
$ 378.00

Alfa Aesar
(R)-(+)-2'-Diphenylphosphino-1,1'-binaphth-2-ol, 96%
50mg
$ 124.00

Total 17 raw suppliers

Chemical Property of (R)-2-Diphenyphosphino-2'-hydroxyl-1,1'-binaphthyl

Chemical Property:

Boiling Point:602.3±43.0 °C(Predicted)
PKA:8.93±0.50(Predicted)
Flash Point:318.1oC
PSA：33.82000
LogP:7.12380
Sensitive.:Air Sensitive

Purity/Quality:

97% ^*data from raw suppliers

(R)-(+)-DIPHENYLPHOSPHINO-2'-HYDROXY-1,1'-BINAPHTHYL 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26-37

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (R)-2-Diphenyphosphino-2'-hydroxyl-1,1'-binaphthyl

There total 16 articles about (R)-2-Diphenyphosphino-2'-hydroxyl-1,1'-binaphthyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 132548-91-5,137769-33-6,162426-75-7
(S)-(+)-2-hydroxy-2'-diphenylphosphinoyl-1,1'-binaphthyl

: 149917-88-4,144868-15-5,199796-91-3
(S)-(-)-2-hydroxy-2'-diphenylphosphino-1,1'-binaphthyl

Guidance literature:: With trichlorosilane; triethylamine; In toluene; at 100 ℃; for 16h;
DOI:10.1021/jo00059a059

Reference yield: 94.0%

: C₃₂H₂₃O₃P

: 149917-88-4,144868-15-5,199796-91-3
(S)-(-)-2-hydroxy-2'-diphenylphosphino-1,1'-binaphthyl

Guidance literature:: With trichlorosilane; In toluene; at 0 - 120 ℃; for 12.5h; Alkaline conditions;
DOI:10.1002/anie.202102352

Reference yield: 73.0%

: (S)-(1,1′-binaphthalen)-2-yldiphenylphosphine oxide

: 149917-88-4,144868-15-5,199796-91-3
(S)-(-)-2-hydroxy-2'-diphenylphosphino-1,1'-binaphthyl

Guidance literature:: (S)-(1,1′-binaphthalen)-2-yldiphenylphosphine oxide; With palladium(II) trifluoroacetate; bis-[(trifluoroacetoxy)iodo]benzene; In nitromethane;

With trichlorosilane; triethylamine;
DOI:10.1021/acscatal.9b04354