fac-{(OC)3Mn(NCMe)(PMe₂Ph)2}PF₆

Base Information

• Chemical Name: fac-{(OC)3Mn(NCMe)(PMe₂Ph)2}PF₆
• CAS No.: 104911-21-9
• Molecular Formula: C₂₁H₂₅MnNO₃P₂*F₆P
• Molecular Weight: 601.284
• Mol file: 104911-21-9.mol

Synonyms:fac-{(OC)3Mn(NCMe)(PMe₂Ph)2}PF₆

Chemical Property of fac-{(OC)3Mn(NCMe)(PMe₂Ph)2}PF₆

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of fac-{(OC)3Mn(NCMe)(PMe₂Ph)2}PF₆

There total 1 articles about fac-{(OC)3Mn(NCMe)(PMe₂Ph)2}PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexafluorophosphoric acid + mer,trans-[Mn(CO)3H(PMe2Ph)2] (61943-37-1,86708-28-3) + acetonitrile (75-05-8,26809-02-9) → Mn(CO)3(NCCH3)(P(CH3)2(C6H5))2(1+)*PF6(1-)=[Mn(CO)3(NCCH3)(P(CH3)2(C6H5))2]PF6 (104911-21-9)

Guidance literature:

In acetonitrile;

DOI:10.1039/DT9760002109

Reference yield: 79.0%

fac-{(OC)3Mn(NCMe)(PMe2Ph)2}PF6 (104911-21-9) → (CO)3Mn(P(CH3)2C6H5)2H (86708-28-3)

Guidance literature:

With hydrogenchloride; In acetonitrile; Electrolysis; Mn-complex dissolved in MeCN containing 0.1 M Et4N(+)PF6(-), electrolysis carried out under Ar with a cathodic current 20 mA at -1.5 V at constant current; catholyte transferred into a Schlenk flask with ether satd. with HCl gas, stirred for 15 min, solvent removed in vac., residue chromd. over florisil using CH2Cl2-ether (10/1);

DOI:10.1021/om00144a023

upstream raw materials:

mer,trans-[Mn(CO)3H(PMe₂Ph)2]

acetonitrile

Downstream raw materials:

(CO)3Mn(P(CH₃)2C₆H₅)2H