2-(benzyloxy)-6,11-dimethoxy-4a-hydroxy-5-(phenylsulfonyl)-1,2,3,4,4a,5,12,12a-octahydronaphthacene

Base Information

Chemical Name:2-(benzyloxy)-6,11-dimethoxy-4a-hydroxy-5-(phenylsulfonyl)-1,2,3,4,4a,5,12,12a-octahydronaphthacene
CAS No.:104847-57-6
Molecular Formula:C₃₃H₃₄O₆S
Molecular Weight:558.695
Hs Code.:

Synonyms:2-(benzyloxy)-6,11-dimethoxy-4a-hydroxy-5-(phenylsulfonyl)-1,2,3,4,4a,5,12,12a-octahydronaphthacene

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Chemical Property of 2-(benzyloxy)-6,11-dimethoxy-4a-hydroxy-5-(phenylsulfonyl)-1,2,3,4,4a,5,12,12a-octahydronaphthacene

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Technology Process of 2-(benzyloxy)-6,11-dimethoxy-4a-hydroxy-5-(phenylsulfonyl)-1,2,3,4,4a,5,12,12a-octahydronaphthacene

There total 2 articles about 2-(benzyloxy)-6,11-dimethoxy-4a-hydroxy-5-(phenylsulfonyl)-1,2,3,4,4a,5,12,12a-octahydronaphthacene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 104847-51-0
1,4-dimethoxy-2-(bromomethyl)-3-<(phenylsulfonyl)methyl>naphthalene

: 4-(benzyloxy)cyclohexanone

: 104847-57-6
2-(benzyloxy)-6,11-dimethoxy-4a-hydroxy-5-(phenylsulfonyl)-1,2,3,4,4a,5,12,12a-octahydronaphthacene

Guidance literature:: With [2,2]bipyridinyl; lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 1h;
DOI:10.1021/jo00248a014

Reference yield: 85.0%

: 2987-06-6
4-(benzyloxy)cyclohexanone

: 104847-51-0
1,4-dimethoxy-2-(bromomethyl)-3-<(phenylsulfonyl)methyl>naphthalene

: 104847-57-6
(4aS,5R)-5-Benzenesulfonyl-2-benzyloxy-6,11-dimethoxy-1,3,4,5,12,12a-hexahydro-2H-naphthacen-4a-ol

Guidance literature:: With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃;
DOI:10.1016/S0040-4039(00)95066-4

Reference yield:

: 104847-57-6
2-(benzyloxy)-6,11-dimethoxy-4a-hydroxy-5-(phenylsulfonyl)-1,2,3,4,4a,5,12,12a-octahydronaphthacene

: 114506-27-3,114506-28-4
2-(benzyloxy)-6,11-dimethoxy-1,2,3,4,12,12a-hexahydronaphthacene

Guidance literature:: With disodium hydrogenphosphate; sodium amalgam; Burgess Reagent; Yield given. Multistep reaction; 1.) RT, 3 h, 2.) 50 deg C, 1 h;
DOI:10.1021/jo00248a014