zinc(II)-5-[4-{3-bromo-2-((4-((2-((6-(pyrimidin-4-yl)pyridin-3-yl)ethynyl)phenyl)ethynyl)phenyl)ethynyl)-5-methyl-1-ylethynyl}benzene]phenyl-10,15,20-trimesitylporphyrin

Base Information

• Chemical Name: zinc(II)-5-[4-{3-bromo-2-((4-((2-((6-(pyrimidin-4-yl)pyridin-3-yl)ethynyl)phenyl)ethynyl)phenyl)ethynyl)-5-methyl-1-ylethynyl}benzene]phenyl-10,15,20-trimesitylporphyrin
• CAS No.: 1380400-90-7
• Molecular Formula: C₈₉H₆₄BrN₇Zn
• Molecular Weight: 1376.83
• Mol file: 1380400-90-7.mol

Synonyms:zinc(II)-5-[4-{3-bromo-2-((4-((2-((6-(pyrimidin-4-yl)pyridin-3-yl)ethynyl)phenyl)ethynyl)phenyl)ethynyl)-5-methyl-1-ylethynyl}benzene]phenyl-10,15,20-trimesitylporphyrin

Chemical Property of zinc(II)-5-[4-{3-bromo-2-((4-((2-((6-(pyrimidin-4-yl)pyridin-3-yl)ethynyl)phenyl)ethynyl)phenyl)ethynyl)-5-methyl-1-ylethynyl}benzene]phenyl-10,15,20-trimesitylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zinc(II)-5-[4-{3-bromo-2-((4-((2-((6-(pyrimidin-4-yl)pyridin-3-yl)ethynyl)phenyl)ethynyl)phenyl)ethynyl)-5-methyl-1-ylethynyl}benzene]phenyl-10,15,20-trimesitylporphyrin

There total 3 articles about zinc(II)-5-[4-{3-bromo-2-((4-((2-((6-(pyrimidin-4-yl)pyridin-3-yl)ethynyl)phenyl)ethynyl)phenyl)ethynyl)-5-methyl-1-ylethynyl}benzene]phenyl-10,15,20-trimesitylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

4-(5-((2-((4-iodophenyl)ethynyl)phenyl)ethynyl)pyridin-2-yl)pyrimidine + C64H51BrN4Zn (1380400-88-3) → zinc(II)-5-[4-{3-bromo-2-((4-((2-((6-(pyrimidin-4-yl)pyridin-3-yl)ethynyl)phenyl)ethynyl)phenyl)ethynyl)-5-methyl-1-ylethynyl}benzene]phenyl-10,15,20-trimesitylporphyrin (1380400-90-7)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In tetrahydrofuran; at 65 ℃; for 18h; Inert atmosphere;

DOI:10.1002/anie.201108089

Reference yield: 70.0%

4-(5-((2-((4-iodophenyl)ethynyl)phenyl)ethynyl)pyridin-2-yl)pyrimidine + C64H51BrN4Zn (1380400-88-3) → ZnN4C20H8(C6H2(CH3)3)3C6H4CCC6H2(CH3)Br(CCC6H4)2CCC5H3NC4H3N2 (1380400-90-7)

Guidance literature:

With Et₃N; Pd(PPh₃)4; In tetrahydrofuran; reflux, 2 d;

DOI:10.1002/anie.201108089

Reference yield:

C119H92BrCuN9Zn(1+)*F6P(1-) → C89H64BrN7Zn (1380400-90-7)

Guidance literature:

With 1,4,8,11-Tetraazacyclotetradecane;

DOI:10.1039/c3dt51780b

upstream raw materials:

C₆₄H₅₁BrN₄Zn

Downstream raw materials:

C₁₂₁H₉₁N₉Zn

C₁₂₁H₉₁N₉Zn